Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- In a different titration experiment, it took 23.95 mL of a 0.175 M solution of NaOH to titrate 20.00 mL of an unknown HCI solution. Calculate the molarity of the HCI solution. HCl(aq) + NaOH (aq) →→→ NaCl (aq) + H₂O (1)arrow_forwardCalculate the pH for each case in the titration of 50.0 mL of 0.120 M HC10(aq) with 0.120 M KOH(aq). Use the ionization constant for HC1O. What is the pH before addition of any KOH? pH = What is the pH after addition of 25.0 mL KOH? pH What is the pH after addition of 40.0 mL KOH? pH What is the pH after addition of 50.0 mL KOH? pH = What is the pH after addition of 60.0 mL KOH? pH :arrow_forward43. A buffer is prepared using acetic acid, CH3COOH, (a weak acid, pKa = 4.75) and sodium acetate, CH3COONa (which provides acetate ions, the conjugate base), according to the following proportions: Volume of CH3COOH(aq): 125.0 mL Concentration of CH3COOH(aq): 1.263 M Volume of CH3COONa(aq): 106.0 mL Concentration of CH3COONa(aq): 1.279 M Determine the volume of 6.00 M HCl required to change the pH of this buffer by one pH unit. 18.15 mL 36.30 mL 21.87 mL 19.30 mL 43.73 mLarrow_forward
- The pH of a 1.00 M NaCH3COO (aq) solution is 9.38. a) HCl (aq) is added to 1.00 L solution of 1.00 M NaCH3COO (aq). Write the chemical reaction between HCl (aq) and NaCH3COO (aq). b) How many mol of HCl (aq) is needed to make a buffer solution with pH = 5.00 from 1.00 L of 1.00 M NaCH3COO (aq)?arrow_forwardHuman blood has a pH of approximately 7.4 due to the carbonic acid/bicarbonate ion (H2CO3/HCO3−) buffer system. Any pH changes below 6.8 or above 7.8 can lead to death! Carbonic acid dissociates to form water and carbon dioxide in the equilibrium shown below. This process is crucial in respiration. H2CO3 (aq) ⇋ CO2 (g) + H2O pKa1 = 2.77 Carbonic acid dissociates in water to form the bicarbonate ion and the hydroxonium ion by the following equilibrium reaction:H2CO3 (aq) + H2O ⇋ H3O(aq)+ + HCO3− pKa2 = 3.70 (i) If there is a 25% increase in carbonic acid levels as per pKa1, explain how the body would deal with this change.arrow_forwardYou want to determine the acid concentration in a can of Sprite and decide to use titration. The chemical reaction that takes place in the titration procedure of a colorless pop or sports drink is represented by the following chemical reaction: H3C6H5O7 (aq) + 3 NaOH (aq) → Na3C6H5O7 (aq)+ 3 H2O (l) If you titrate 20.00 mL of Sprite with 5.85 mL of 0.125 M NaOH, what is the concentration (Molarity) of in this wine?arrow_forward
- Hello! If you could please help me with this questionarrow_forward7.7 g of citric acid (MM = 192.1 g/mol) can be titrated with NaOH according to the following balanced chemical equation. H3C6H5O7 (aq) + NaOH(aq) → H2O(l) + Na H2C6H5O7(aq) what would the curve for the titration of the neutralization of the three hydrogens of this acid with NaOH look like?arrow_forward+ pH Changes in Buffers When a solution contains a weak acid and its conjugate base or a weak base and its conjugate acid, it will be a buffer solution. Buffers resist change in pH following the addition of acid or base. A buffer solution prepared from a weak acid (HA) and its conjugate base (A) is represented as HA (aq) → H¹ (aq) + A (aq) The buffer will follow Le Châtelier's principle. If acid is added, the reaction shifts to consume the added H+, forming more HA. When base is added, the base will react with H+, reducing its concentration. The reaction then shifts to replace H+ through the dissociation of HA into H+ and A™. In both instances. [H] tends to remain constant. The pH of a buffer is calculated by using the Henderson-Hasselbalch equation: A] pH =pK₂ +log HA ▼ Part A pH = What is the pH of a buffer prepared by adding 0.607 mol of the weak acid HA to 0.507 mol of NaA in 2.00 L of solution? The dissociation constant K₁ of HA is 5.66 x 10-7 Express the pH numerically to three…arrow_forward
- A solution of malonic acid, H2C3H2O4H2C3H2O4 , was standardized by titration with 0.1000 M NaOHNaOH solution. If 21.68 mLmL of the NaOHNaOH solution were required to neutralize completely 13.00 mLmL of the malonic acid solution, what is the molarity of the malonic acid solution? H2C3H2O4+2NaOH→Na2C3H2O4+2H2OH2C3H2O4+2NaOH→Na2C3H2O4+2H2Oarrow_forward2. Dr. Dahm has prepared 250 mL of a acetate buffer which contains 0.1 mol of acetic acid (CH₂COOH) and 0.15 moles of acetate (CH₂COO). Determine the initial pH. If he then adds 0.025 moles of H* calculate the new pH. Ka = 1.8 × 10³ CH₂COOH(aq) + H₂O CH₂COO (aq) + HO (aq) 3. Dr. Dahm makes a second acetate buffer exactly the same way as in #2, but he then adds 15 mL of 0.50 M NaOH calculate the new pH.arrow_forward5. Calculate the pH for each case in the titration of 50.0 mL of 0.230 M HClO(aq) with 0.230 M KOH(aq). Use the ionization constant for HClO. What is the pH before addition of any KOH? KCIO constant = 4.0x10^-8 What is the pH after addition of 25.0 mL KOH? What is the pH after addition of 40.0 mL KOH? What is the pH after addition of 50.0 mL KOH? What is the pH after addition of 60.0 mL KOH?arrow_forward
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