For the reaction Cr(C6H6)2 (s) --> Cr(s) + 2 C6H6 (g), the reaction internal energy change at 1 atm and 538 K is DUrxno(T = 538K) = 8.0 kJ/mol. (a) Estimate the molar enthalpy of reaction at 1 atm and 538 K for the above reaction. (b) If the standard molar enthalpy of formation for C6H6 at 1 atm and 538 K is about DHfo (C6H6 (g)) =  84 kJ/mol, estimate the standard enthalpy of formation of Cr(C6H6)2 (s) at 1 atm and 538 K.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

For the reaction Cr(C6H6)2 (s) --> Cr(s) + 2 C6H6 (g), the reaction internal energy change at 1 atm and 538 K is DUrxno(T = 538K) = 8.0 kJ/mol.

(a) Estimate the molar enthalpy of reaction at 1 atm and 538 K for the above reaction.

(b) If the standard molar enthalpy of formation for C6H6 at 1 atm and 538 K is about DHfo (C6H6 (g)) =  84 kJ/mol, estimate the standard enthalpy of formation of Cr(C6H6)2 (s) at 1 atm and 538 K.

Expert Solution
Step 1

The internal energy change can be calculated by the following formula.

H=U-n(g)RTU=change in internal energyH=change in enthalpyn(g)=change in moles of gaseous atomsR=gas constantT-temperature

The standard enthalpy of reaction have the following formula.

H0reaction=nHf0products-nHf0reactantsHf0products=standard molar enthalpy of formation of productsHf0reactants=standard molar enthalpy of formation of reactants

steps

Step by step

Solved in 3 steps

Blurred answer
Knowledge Booster
Thermodynamics
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY