For the mechanism provided below: a. Write the balanced equation for the overall reaction. b. Use the mechanism to write a predicted rate law (using Equality of Rates to replace intermediate species if applicable). c. State the relationship between the rate constant k to the rate constants in the mechanism's elementary reactions.

Pushing Electrons
4th Edition
ISBN:9781133951889
Author:Weeks, Daniel P.
Publisher:Weeks, Daniel P.
Chapter3: Mechanisms
Section: Chapter Questions
Problem 64EQ
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Mechanism:
Step 1 (used twice to reach overall reaction): N205 (g)
NO2 (g) + NO3 (g)
fast, reversible
Step 2:
NO2 (g) + NO3 (g) k2 NO (g) + NO2 (8) + O2
(g)
slow
Step 3:
NO (g) + NO3 (g) *3 2NO2 (g)
fast
Transcribed Image Text:Mechanism: Step 1 (used twice to reach overall reaction): N205 (g) NO2 (g) + NO3 (g) fast, reversible Step 2: NO2 (g) + NO3 (g) k2 NO (g) + NO2 (8) + O2 (g) slow Step 3: NO (g) + NO3 (g) *3 2NO2 (g) fast
For the mechanism provided below:
a. Write the balanced equation for the overall reaction.
b. Use the mechanism to write a predicted rate law (using Equality of Rates to replace
intermediate species if applicable).
c. State the relationship between the rate constant k to the rate constants in the
mechanism's elementary reactions.
Transcribed Image Text:For the mechanism provided below: a. Write the balanced equation for the overall reaction. b. Use the mechanism to write a predicted rate law (using Equality of Rates to replace intermediate species if applicable). c. State the relationship between the rate constant k to the rate constants in the mechanism's elementary reactions.
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