Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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For the hydroxyl rotation of vinyl alcohol, which conformation (1 or 2) would be more stable and why? Below is some helpful information. Thank you :)

Molecule Electronic energy Zero point vibrational energy
Conformation 1 -153.805672 0.056715
Conformation 2 -153.802228 0.056237
Transition state -153.796260 0.055361

Energy difference between conformations 1 and 2: -9.04 kJ mol-1

Reaction barrier (activation energy) of the rotation: 21.2 kJ mol-1

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