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- rank these from least to most reactive in nucleophilic acyl substitution with a nucleophile I)CH3COOC2H5 II) CH3COO-Na+ III)CH3COCl IV) CH3CONH2Write out the expected splitting pattern for hydrogens Ha, Hp and Hc 3Jab = 10 Hz На Hb 3Jpc = 7 Hz CI Hc Hc Ha:Hb:Hc: doublet, quartet, doublet Ha:Hb:Hc: quartet, quartet, triplet Ha:Hb:Hc: doublet, doublet of triplets, doublet Ha:Hb:Hc: doublet, triplet of doublets, doublet4) Vocabulary: words are given circle the correct one. a. A Robinson Annulation can occur with acetoacetate / malonic ester / both / neither Fill in the blanks with the appropriate vocabulary word. If two as the nucleophile, and with conjugated ester / conjugated ketone / epoxide / all/ none as the electrophile. The Robinson Annulation is a reaction followed by a reaction and always / sometimes / never gives a 6-member ring. b. It is always / sometimes / never possible to use base to form an acyl anion directly from an aldehyde. c. True / False.Aliphatic heterocycles typically react like linear versions of the functional group. d. Claisen condensations require catalytic / 1 equivalent / large excess base, at least 2 alpha hydrogens on the nucleophile, always / sometimes / never use an ester as an electrophile, and always / sometimes / never use an ester as a nucleophile. e. Reaction of a beta-ketoester with water, acid, and heat gives first a reaction, then and lastly This reaction…
- This proposed alpha-alkylation reaction would not work. Identify what is wrong with it. ан 1. LiN-Pr₂/THF 2. CH3CH2Br CH3 A) This reaction would require a different solvent. B) The wrong base was used. C) There is a problem with the order of addition. D) The nucleophile isn't appropriate for this electrophile.n. Label the reactive features of each molecule and then circle the nucleophile used in the reaction when the electrophile is highly reactive (IVS! or strained ring). Also, write the reason why you selected that electrophile. Br H3C-ọ or HSynthesize the following compound from cyclohexanol using any other organic or inorganic compounds. HO. Part 1 out of 2 Preparation of the Grignard reagent: Book rint rences OH draw structure ... draw structure... Draw the intermediate product formed above and select the correct reagent A. O MgBr, O CH;Br O Brz PB13 Draw the intermediate product formed above and select the correct reagent B. O MgBr O Mgo O O Mgl, O Mg Hint Prev 3 of .8 Next > re to search
- 3. Draw all products for the following reactions. For your products, write whether the nucleophile added to the Re face or Si face of the starting material. a. HO b. 1) LIAIH 2) H™ 1) CH3CH2Li 2) H+ c) Determine whether the nucleophile added to the Re face or Si face of benzaldehyde.An SN2 mechanism takes place when 3-(bromomethyl)pentane is added to each nucleophile listed below. Which nucleophile will also require an acid-base step after the substitution step in order to produce a neutral (not charged) product? A. LiN(CH3)2 B. NaI C. KN3 D. HSCH3 (Please type answer no write by hend)2. Draw the structures and explain why CH3CH₂O and CH3CO₂ are good nucleophiles but CH3SO3, water, and alcohols (R-OH) are poor nucleophiles. Propose a 'cutoff' for the amount of negative charge needed to be a good nucleophile. CH3CH₂O CH3CO₂ CH3SO3 H₂O CH₂OH
- Draw the major product of the reaction sequence. Omit byproducts. Select Draw Rings More C H 1. PHCO0OH 2. EtLi, then H3O* 3. PCCWhich of the following compounds reacts faster in an elimination reaction with KOH? Also provide the major product(s) (if any) for each elimination reaction. Br Br )...Can you match best nucleophile / conditions from the list that will give a successful hydrolysis reaction for each electrophile? (there's one best nucleophile / conditions for each electrophile) <List for Nucleophile / condition> a. LiAlH4; hydronium work-up b. PCC c. NaH d. CrO3 e. HOEt f. H3O+ or OH- g. H2O h. NaBH4;hydronium work-up Electrophile 1. Acid chloride 2. Acetic anhydride 3. Ester 4. Amide I'm asking again on bartleby because pther tutor gave me the right answer because I think I didn't make my question clear enough.