
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Transcribed Image Text:For each of the processes, determine whether the entropy of the system is increasing or decreasing. The system
is underlined.
Entropy is increasing
Entropy is decreasing
Answer Bank
a snowman melts on a spring day
a water bottle cools down in a refrigerator
iron rusts to iron oxide
a document goes through a paper shredder
dissolved sugar precipitates out of water to form rock candy
Expert Solution

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Step 1
Here are some points to easily identify the direction of change in entropy of physical processes-
- Entropy is always assisted by the term "randomness" and "disorder". So, an increase in these two in any case will always be assisted with an increase in the entropy of the system,
- So, from the above point, we can figure it out easily that, solid substances are more ordered and with least entropy, then comes liquid and at last the gases are the most disordered. So, on going from, solid>liquid then gas, entropy always increases,
- Heating is always associated with an increase in entropy and cooling is associated with a decrease in entropy,
- In general, spontaneous processes are associated with an increase in entropy of the system(though not always!) and the processes that involve any external force i.e. non-spontaneous processes are associated with decrease in entropy.
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- Classify each of the statements as true or false. True False Answer Bank Entropy decreases as the temperature increases. The entropy of a substance decreases when a gas condenses into a liquid at any temperature. A reaction will have an equilibrium constant that is greater than one if AG° for the reaction is negative. For an exothermic reaction, an increase in temperature results in a decrease in the equilibrium constant. Product formation is always favored in a reaction with a negative AH° and a negative ASº. An exothermic reaction is always spontaneous.arrow_forwardpredict whether each of the following processes increases or decreases entropy and explain your reasoning. a. burning a log in a fireplace b. condensing of water vapor on a cold surfacearrow_forwardAll the following involve an increase in entropy except most endothermic reactions sublimation vaporization combustionarrow_forward
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