Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- In this lab, we will experimentally determine the titration curve for the titration of a weak acid solution against a strong base solution. The weak acid we will use is potassium hydrogen phthalate, KHP, its chemical structure is shown below. KHP is an ionic compound composed of a potassium cation K+ and a hydrogen phthalate anion HP–. HP– is a weak acid and upon dissolving in water, can lower the pH of the solution. (a) Suggest the chemical reaction(s) when a solid sample of KHP is dissolved in water, writing out the chemical equations for them. (b) Sketch the structure of KHP from above and circle the hydrogen atom that is responsible for its acidity. (c) Calculate the pH of a solution made of 0.50 g of KHP and 50 mL of water. KHP has a molar mass of 204.2 g and at 25 °C has a pKa of 5.4.arrow_forwardHydrofluoric acid is important in both pharmaceutical synthesis and the synthesis of Teflon. It can be produced by reacting H2 with F2, H2(g) + F2(g)-> 2 HF(g). If you ran the reaction with initial concentrations of H2 and F2 2.00M, what would the concentration of HF be at equilibrium? The Kc =115. a. 3.37 M Ob. 0.85 M Oc. C. 1.69 M Od. 4.00 M le. 2.85 Marrow_forwardKSP for Copper Sulfide is: 7.9 × 10-37 KSP for Copper Hydroxide is: 1.6 × 10-19arrow_forward
- Chemistry Determine the pH of a buffer solution by constructing an ICE table, writing the equilibrium constant expression, and using this information to determine the pH. Complete Parts 1-3 before submitting your answer. NEXT > The buffer was prepared by dissolving 20.0 g NaCH,CO0 into a 500.0 mL solution of 0.150 M of CH,COOH. Assume the volume of the solution does not change. Fill in the ICE table with the appropriate value for each involved species to determine concentrations of all reactants and products. CH,COOH(aq) + H,O(1) H,O"(aq) + CH,COO (aq) Initial (M) Change (M) Equilibrium (M) 5 RESET 20.0 0.150 0.244 0.488 0.678 20.0+ 20.0- 0150 +1 0.150- 0.244+ 0.488 0.244- 0.488-x 0678 0.678-1 Determine the pH of a buffer solution by constructing an ICE table, writing the equilibrium constant expression, and using this information to determine the pH. Complete Parts 1-3 before submitting your answer. NEXT ( PREV The Ka for CH,COOH, is 1.8 x 10, Based on your ICE table (Part 1) and the…arrow_forwardThe initial in the unknown analysis is the addition of 6. M HCl. This results in the formation of a precipitate. The solid precipitate is separate from the liquid solution. The solution could potentially contain K+, Ca2+, and Al3+. Next, 3M NH3 is added to the solution to separate the Al3+. This is a result of the fact that the Al3+ forms the hydroxide, Al(OH)3. But Ca2+ also forms the hydroxide, Ca(OH)2. Why does the Ca(OH)2 not separate out with the Al(OH)3?arrow_forwardFor each of the following compounds, decide whether the compound's solubility in aqueous solution changes with pH. If the solubility does change, pick the pH at which you'd expect the highest solubility. You'll find K data in the ALEKS Data tab. sp highest solubility Does solubility change with compound pH? PH = 6 pH = 7 pH = 8 yes BaCO3 no yes Ar Cal2 no yes Cu Br no X Ś ?arrow_forward
- A buffer solution contains 0.305 M hydrocyanic acid and 0.379 M sodium cyanide. If 0.0518 moles of potassium hydroxide are added to 225 mL of this buffer, what is the pH of the resulting solution ? (Assume that the volume does not change upon adding potassium hydroxide. ) pH %3Darrow_forwardCalculate the solubility at 25 °C of Ni(OH)2 in pure water and in a 0.0170M NaOH solution. You'll find K sp Round both of your answers to 2 significant digits. solubility in pure water: solubility in 0.0170 M NaOH solution: 0- 00 x10 X ☐☐ 5 010 data in the ALEKS Data tab.arrow_forwardPlease don't provide handwritten solution ....arrow_forward
- Based on your ICE table (Part 1) and the definition of Kb, set up the expression for Kb in order to determine the unknown. Each reaction participant must be represented by one tile. Do not combine terms. Kb = = 5.2 × 10-4 RESET [0] [0.075] [0.10] [5.2 × 10] [x] [2x] [2x]² [0.075 + x] [0.075 - x] [0.075 + 2x] [0.075 - 2x] [0.10+x] [0.10 - x] [0.10 + 2x] [0.10 -2x] < PREV 2 3 Based on your ICE table (Part 1) and the equilibrium expression for Kb (Part 2), determine the pH of the solution. pH = RESET 0 7.86 6.14 0.075 3.9 × 10 3.41 10.59 1.12arrow_forward0.030 moles of a weak acid, HA, was dissolved in 2.0 L of water to form a solution. At equilibrium, the concentration of HA was found to be 0.013 M. Determine the value of Ka for the weak acid. 1 NEXT > Based on the given values, fill in the ICE table to determine concentrations of all reactants and products. H¿O(I) H.O*(aq) A (aq) + НА(ag) Initial (M) Change (M) Equilibrium (M) 5 RESET 0.060 0.015 0.017 0.030 0.013 2.0 8 2/ pe here to search DELL 1Larrow_forwardComplete the following solubility constant expression for PbCrO 4. K sp = 0 X Śarrow_forward
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