Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- The oxidation of glucose, C6H12O6(s), is described by the following thermochemical equation:C6H12O6(s) + 6 O2(g) → 6 CO2(g) + 6 H2O(l) ΔH = -2772 kJHow much heat, in kilojoules, can be produced by the oxidation of 3.56 g of fuel C6H12O6?Molar mass of C6H12O6 = 180.156 g/molarrow_forwardPart B 2.0000 g of the unknown compound is burned in a bomb calorimeter. During the combustion, the temperature of the calorimeter increases from 23.125°C to 28.997 °C. During calibration, the heat capacity of the calorimeter was found to be 9.9897kJ °C-1. In the previous experiment, the molar mass of the substance was found to be 148.16 gmol-1. What is AcombU for the unknown compound? να ΑΣφ ? kJ mol1 Submit Request Answerarrow_forwardGiven: 4AICI3(s) + 302(g) → 2Al,O3(s) + 6C12(g); AH=-529.0 kJ determine AH for the following thermochemical equation. Cl,(3) + Al,O;(s) → AICI,(9) + 02(g) O +88.2 kJ O +264.5 kJ O +176.3 kJ O -176.3 kJ O +529.0 kJarrow_forward
- To study the possible amount of energy generated by a person, the person can be roughly viewed as a constant pressure calorimeter using table sugar (sucrose, C12H22O11) as the energy generator. The reaction of table sugar in a calorimeter is given by: C12H22O11(s) + 12O2(g) ----------> 12CO2(g) + 11H2O(g) a. What is the heat released by consuming one mole of sugar (C12H22O11) in this way? b. Calculate the enthalpy of combustion per mole of sugar utilization. c. Does the result of your calculation make sense?arrow_forwardA piece of metal of mass 15 g at 99◦C is placed in a calorimeter containing 41.3 g of water at 19◦C. The final temperature of the mixture is 40.2◦C. What is the specific heat capacity of the metal? Assume that there is no energy lost to the surroundings. Answer in units ofJg·◦C.arrow_forwardThe table provides molar heat capacities (Cm) of selected metals with the units of joules per mole-kelvin. Heat capacity is also frequently given as specific heat capacity (C₂) with the units joules per gram-degree Celsius. Using the values provided in the table, convert the molar heat capacity (Cm) of zinc to the specific heat capacity (C₂) of zinc. C₁ = J/(g. °C) Molar heat capacity (Cm) of selected metals at 25 °C Element aluminum copper iron lead magnesium nickel titanium zinc Cm (J/(mol-K)) 24.20 24.44 25.10 26.84 24.87 26.07 25.06 25.39arrow_forward
- The molar heat capacity at constant pressure of carbon dioxide is 29.14 J/K.mol. (a) What is the value of its molar heat capacity at constant volume? _______ J/K/mol. 4 sig. number (b) Calculate the change in enthalpy when 1 mole carbon dioxide is heated from 15°C (the temperature when the air is inhaled) to 37°C (blood temperature, the temperature in our lungs)? _______ J/mol. 4 sig. number normal format. (c) Calculate molar internal energy when carbon dioxide is heated from 19.58 °C (the temperature when the air is inhaled) to 37°C (blood temperature, the temperature in our lungs). ______ J/mol. 3 sig. number normal format.arrow_forwardAt constant volume, the heat of combustion of a particular compound is -3916.0 kJ/mol. When 1.329 g of this compound (molar mass = 166.62 g/mol) was burned in a bomb calorimeter, the temperature of the calorimeter, including its contents, rose by 7.549 "C. What is the heat capacity (calorimeter constant) of the calorimeter? calorimeter constant: kJ/ "Carrow_forwardFructose, C6H12O6(s), is a sugar closely related to glucose.. A 0.755 g sample of fructose was combusted with excess oxygen in a bomb calorimeter, containing 500.0 g of water. The heat capacity of the empty calorimeter was 208 J/K. The temperature of the calorimeter and the water rose from 22.00°C to 27.12°C due to the combustion reaction, which formed CO2(g) and liquid water. What is the energy change, AU (in kJ), for the combustion of one mole of fructose under these conditions? -15600 -2810 +520 +254 -804arrow_forward
- How many grams of CaO must be added to 50.0 mL of water to make the temperature increase from 25.0 °C to 58.87 °C? The reaction is CaO(s) + H 2O(l) ↔ Ca(OH) 2(aq) -- ΔH = -83.7 kJAssume the heat capacity of the solution is the same as pure water (4.184 J/g*°C), the density of the solution is 1.00 g/mL and there is no loss of heat to the surroundings.arrow_forwardGasoline is composed primarily of hydrocarbons, includingmany with eight carbon atoms, called octanes. One ofthe cleanest–burning octanes is a compound called 2,3,4-trimethylpentane, which has the following structural formula: The complete combustion of one mole of this compoundto CO21g2 and H2O1g2 leads to ΔH° = -5064.9 kJ.(a) Write a balanced equation for the combustion of1 mol of C8H181l2. (b) By using the information inthis problem and data in Table 5.3, calculate ΔHf° for2,3,4-trimethylpentane.arrow_forward(1)Consider the reaction: 2A (g) + 3 B (g) → 2 C (g) ΔHrxn = +254.3 kJ What will be the enthalpy change (in kJ) if 0.471 mol B reacts in excess A? (2)Consider the reaction: C (s) + O2 (g) → CO2 (g) ΔHrxn = -393.5 kJ What mass of carbon (in g) must be reacted via this mechanism to release 581.2 kJ of heat?arrow_forward
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