Find the concentration of I in 0.050 M AgNO3 saturated with AgI. Include activity coefficients in the solubility-product expression. The Ksp of AgI is 8.3 × 10-¹7. Refer to the table of activity coefficients at various ionic strengths as needed. [r] = M

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

Reference table provided

Find the concentration of I in 0.050 M AgNO3 saturated with AgI. Include activity coefficients in the solubility-product
expression. The K sp of AgI is 8.3 × 10-¹7. Refer to the table of activity coefficients at various ionic strengths as needed.
[r] =
M
Transcribed Image Text:Find the concentration of I in 0.050 M AgNO3 saturated with AgI. Include activity coefficients in the solubility-product expression. The K sp of AgI is 8.3 × 10-¹7. Refer to the table of activity coefficients at various ionic strengths as needed. [r] = M
Ion
H™
Charge= +/-1
(C6H5)2CHCO2, (C3H7)4N+
(O₂N)3C6H₂O,(C3H7)NH*,CH3O6H4CO2-
Lit,C6H5CO₂, HỌC6H4CO2-, C¹C6H4CO2-, C6H5CH₂CO2,
CH₂=CHCH₂CO2-,(CH3)2CHCH₂CO2-, (CH3CH2)4N+, (C3H7)2NH2+
Cl₂CHCO2, C13CCO2, (CH3CH₂)3NH¹, (C3H7)NH3+
Nat, CdC1, C1O₂, 103, HCO3, H₂PO4, HSO3, H₂AsO4",
Co(NH3)4(NO₂)2, CH3CO₂, CICH₂CO₂¯, (CH3)4N*, (CH3CH₂)2NH₂*,
H₂NCH₂CO₂
*H3NCH₂CO₂H,(CH3)3NH+, CH3CH₂NH3+
OH, F, SCN, OCN¯, HS¯, ClO3¯`, C1O4¯, BrO3¯, IO4¯`, MnO4, HCO₂,
H₂citrate", CH3NH3*, (CH3)2NH₂+
K, Cl, Br, I, CN, NO₂, NO3
Rbt, Cst, NH4+, TI+, Ag+
Charge= +/-2
Mg2+, Be2+
CH₂(CH₂CH₂CO2)2, (CH₂CH₂CH₂CO2-)2
Ca²+, Cu²+, Zn²+, Sn²+, Mn²+, Fe+2, Ni²+, Co2, C6H4(CO₂)2,
H₂C(CH₂CO2)2, (CH₂CH₂CO2)2
Sr²+, Ba²+, Cd2+, Hg2+, S²-, S₂04²-, WO4², H₂C(CO₂)2, (CH₂CO₂)2,
(CHOHCO₂)2
2+
Pb 2+, CO 3²-, SO 3²-, MoO 4²-, Co(NH 3 ) 5 C1 ²+, Fe(CN) 5 NO ²-,c
2 04²-, Hcitrate 2-
2+
Hg₂+, SO4²-, S₂O32-, $₂06²-, S₂Og²-, SO4²-, CrO4²-, HPO4²-
Th4+, Zr4+, Ce4+, Sn4+
Fe(CN)64-
Charge= +/- 3
Al³+, Fe3+, Cr³+, Sc³+, y³+, In³+, lanthanidesa
citrate 3-
PO4³-, Fe(CN)6³-, Cr(NH3)6³+, Co(NH3)6³+, C0(NH3)5H₂O³+
Charge = +/- 4
Ion
size
(a ,pm)
900
800
700
600
500
450
400
350
300
250
800
700
600
500
450
400
900
500
400
1100
500
0.001 0.005
0.967 0.933
0.966
0.931
0.965 0.930
0.965
0.964 0.928
0.964
0.964
0.964
0.964
0.964
0.872
0.872
0.868
0.867
0.929
0.738
0.728
0.725
0.928
0.588
0.57
0.927
0.870 0.749
0.926
0.925
0.924
0.755
0.755
0.744
0.867 0.740
0.742
0.54
0.51
0.505
0.35
0.31
Ionic Strength(μ,M)
0.01
Activity coefficient (y)
0.914
0.912
0.909
0.907
0.904
0.902
0.901
0.900
0.899
0.898
Activity coefficient (y)
0.69
0.685
0.675
0.67
0.665
0.660
Activity coefficient (y)
0.445
0.405
0.395
Activity coefficient (y)
0.255
0.20
0.05
0.86
0.85
0.845
0.835
0.83
0.82
0.815
0.81
0.52
0.50
0.485
0.465
0.455
0.1
0.245
0.18
0.16
0.83
0.82
0.10
0.048
0.81
0.805 0.755
0.80
0.75
0.80
0.79
0.775
0.77
0.76
0.45
0.425
0.405
0.38
0.445 0.355
0.37
0.18
0.115
0.095
0.065
0.021
Transcribed Image Text:Ion H™ Charge= +/-1 (C6H5)2CHCO2, (C3H7)4N+ (O₂N)3C6H₂O,(C3H7)NH*,CH3O6H4CO2- Lit,C6H5CO₂, HỌC6H4CO2-, C¹C6H4CO2-, C6H5CH₂CO2, CH₂=CHCH₂CO2-,(CH3)2CHCH₂CO2-, (CH3CH2)4N+, (C3H7)2NH2+ Cl₂CHCO2, C13CCO2, (CH3CH₂)3NH¹, (C3H7)NH3+ Nat, CdC1, C1O₂, 103, HCO3, H₂PO4, HSO3, H₂AsO4", Co(NH3)4(NO₂)2, CH3CO₂, CICH₂CO₂¯, (CH3)4N*, (CH3CH₂)2NH₂*, H₂NCH₂CO₂ *H3NCH₂CO₂H,(CH3)3NH+, CH3CH₂NH3+ OH, F, SCN, OCN¯, HS¯, ClO3¯`, C1O4¯, BrO3¯, IO4¯`, MnO4, HCO₂, H₂citrate", CH3NH3*, (CH3)2NH₂+ K, Cl, Br, I, CN, NO₂, NO3 Rbt, Cst, NH4+, TI+, Ag+ Charge= +/-2 Mg2+, Be2+ CH₂(CH₂CH₂CO2)2, (CH₂CH₂CH₂CO2-)2 Ca²+, Cu²+, Zn²+, Sn²+, Mn²+, Fe+2, Ni²+, Co2, C6H4(CO₂)2, H₂C(CH₂CO2)2, (CH₂CH₂CO2)2 Sr²+, Ba²+, Cd2+, Hg2+, S²-, S₂04²-, WO4², H₂C(CO₂)2, (CH₂CO₂)2, (CHOHCO₂)2 2+ Pb 2+, CO 3²-, SO 3²-, MoO 4²-, Co(NH 3 ) 5 C1 ²+, Fe(CN) 5 NO ²-,c 2 04²-, Hcitrate 2- 2+ Hg₂+, SO4²-, S₂O32-, $₂06²-, S₂Og²-, SO4²-, CrO4²-, HPO4²- Th4+, Zr4+, Ce4+, Sn4+ Fe(CN)64- Charge= +/- 3 Al³+, Fe3+, Cr³+, Sc³+, y³+, In³+, lanthanidesa citrate 3- PO4³-, Fe(CN)6³-, Cr(NH3)6³+, Co(NH3)6³+, C0(NH3)5H₂O³+ Charge = +/- 4 Ion size (a ,pm) 900 800 700 600 500 450 400 350 300 250 800 700 600 500 450 400 900 500 400 1100 500 0.001 0.005 0.967 0.933 0.966 0.931 0.965 0.930 0.965 0.964 0.928 0.964 0.964 0.964 0.964 0.964 0.872 0.872 0.868 0.867 0.929 0.738 0.728 0.725 0.928 0.588 0.57 0.927 0.870 0.749 0.926 0.925 0.924 0.755 0.755 0.744 0.867 0.740 0.742 0.54 0.51 0.505 0.35 0.31 Ionic Strength(μ,M) 0.01 Activity coefficient (y) 0.914 0.912 0.909 0.907 0.904 0.902 0.901 0.900 0.899 0.898 Activity coefficient (y) 0.69 0.685 0.675 0.67 0.665 0.660 Activity coefficient (y) 0.445 0.405 0.395 Activity coefficient (y) 0.255 0.20 0.05 0.86 0.85 0.845 0.835 0.83 0.82 0.815 0.81 0.52 0.50 0.485 0.465 0.455 0.1 0.245 0.18 0.16 0.83 0.82 0.10 0.048 0.81 0.805 0.755 0.80 0.75 0.80 0.79 0.775 0.77 0.76 0.45 0.425 0.405 0.38 0.445 0.355 0.37 0.18 0.115 0.095 0.065 0.021
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps with 2 images

Blurred answer
Knowledge Booster
Equilibrium Concepts in Analytical Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY