Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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![Find the concentration of I in 0.050 M AgNO3 saturated with AgI. Include activity coefficients in the solubility-product
expression. The K sp of AgI is 8.3 × 10-¹7. Refer to the table of activity coefficients at various ionic strengths as needed.
[r] =
M](https://content.bartleby.com/qna-images/question/af8dd5bb-1368-4a10-9929-9294802d0b74/337bc752-a156-4f6e-b66e-33e1a5135d0f/kkilkr_processed.png)
Transcribed Image Text:Find the concentration of I in 0.050 M AgNO3 saturated with AgI. Include activity coefficients in the solubility-product
expression. The K sp of AgI is 8.3 × 10-¹7. Refer to the table of activity coefficients at various ionic strengths as needed.
[r] =
M
Transcribed Image Text:Ion
H™
Charge= +/-1
(C6H5)2CHCO2, (C3H7)4N+
(O₂N)3C6H₂O,(C3H7)NH*,CH3O6H4CO2-
Lit,C6H5CO₂, HỌC6H4CO2-, C¹C6H4CO2-, C6H5CH₂CO2,
CH₂=CHCH₂CO2-,(CH3)2CHCH₂CO2-, (CH3CH2)4N+, (C3H7)2NH2+
Cl₂CHCO2, C13CCO2, (CH3CH₂)3NH¹, (C3H7)NH3+
Nat, CdC1, C1O₂, 103, HCO3, H₂PO4, HSO3, H₂AsO4",
Co(NH3)4(NO₂)2, CH3CO₂, CICH₂CO₂¯, (CH3)4N*, (CH3CH₂)2NH₂*,
H₂NCH₂CO₂
*H3NCH₂CO₂H,(CH3)3NH+, CH3CH₂NH3+
OH, F, SCN, OCN¯, HS¯, ClO3¯`, C1O4¯, BrO3¯, IO4¯`, MnO4, HCO₂,
H₂citrate", CH3NH3*, (CH3)2NH₂+
K, Cl, Br, I, CN, NO₂, NO3
Rbt, Cst, NH4+, TI+, Ag+
Charge= +/-2
Mg2+, Be2+
CH₂(CH₂CH₂CO2)2, (CH₂CH₂CH₂CO2-)2
Ca²+, Cu²+, Zn²+, Sn²+, Mn²+, Fe+2, Ni²+, Co2, C6H4(CO₂)2,
H₂C(CH₂CO2)2, (CH₂CH₂CO2)2
Sr²+, Ba²+, Cd2+, Hg2+, S²-, S₂04²-, WO4², H₂C(CO₂)2, (CH₂CO₂)2,
(CHOHCO₂)2
2+
Pb 2+, CO 3²-, SO 3²-, MoO 4²-, Co(NH 3 ) 5 C1 ²+, Fe(CN) 5 NO ²-,c
2 04²-, Hcitrate 2-
2+
Hg₂+, SO4²-, S₂O32-, $₂06²-, S₂Og²-, SO4²-, CrO4²-, HPO4²-
Th4+, Zr4+, Ce4+, Sn4+
Fe(CN)64-
Charge= +/- 3
Al³+, Fe3+, Cr³+, Sc³+, y³+, In³+, lanthanidesa
citrate 3-
PO4³-, Fe(CN)6³-, Cr(NH3)6³+, Co(NH3)6³+, C0(NH3)5H₂O³+
Charge = +/- 4
Ion
size
(a ,pm)
900
800
700
600
500
450
400
350
300
250
800
700
600
500
450
400
900
500
400
1100
500
0.001 0.005
0.967 0.933
0.966
0.931
0.965 0.930
0.965
0.964 0.928
0.964
0.964
0.964
0.964
0.964
0.872
0.872
0.868
0.867
0.929
0.738
0.728
0.725
0.928
0.588
0.57
0.927
0.870 0.749
0.926
0.925
0.924
0.755
0.755
0.744
0.867 0.740
0.742
0.54
0.51
0.505
0.35
0.31
Ionic Strength(μ,M)
0.01
Activity coefficient (y)
0.914
0.912
0.909
0.907
0.904
0.902
0.901
0.900
0.899
0.898
Activity coefficient (y)
0.69
0.685
0.675
0.67
0.665
0.660
Activity coefficient (y)
0.445
0.405
0.395
Activity coefficient (y)
0.255
0.20
0.05
0.86
0.85
0.845
0.835
0.83
0.82
0.815
0.81
0.52
0.50
0.485
0.465
0.455
0.1
0.245
0.18
0.16
0.83
0.82
0.10
0.048
0.81
0.805 0.755
0.80
0.75
0.80
0.79
0.775
0.77
0.76
0.45
0.425
0.405
0.38
0.445 0.355
0.37
0.18
0.115
0.095
0.065
0.021
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