Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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0.01
0.02
0.04
0.05
0.06
E00
[DER], M
Figure A. Rate of the reaction with increasing DER concentration while
BLOOD and BEN concentrations are constant.
1. What is the order of reaction with respect to DER?
2. Calculate for the concentration of BLOOD after mixing for Runs 2 (x)
and 3 (y). Run 2:
Run 3:
3. Determine the order of the reaction with respect to BLOOD. Round
off the answer to the nearest whole number.
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Transcribed Image Text:0.01 0.02 0.04 0.05 0.06 E00 [DER], M Figure A. Rate of the reaction with increasing DER concentration while BLOOD and BEN concentrations are constant. 1. What is the order of reaction with respect to DER? 2. Calculate for the concentration of BLOOD after mixing for Runs 2 (x) and 3 (y). Run 2: Run 3: 3. Determine the order of the reaction with respect to BLOOD. Round off the answer to the nearest whole number.
CHEMICAL KINETICS
AVATAR reaction shown below was subjected to method of initial rates to
determine its rate constant.
BLOOD + BEN + DER → KATARA
The data on the preparation of KATARA and the results of the experiment
are presented below.
Table 1. Data on the preparation of KATARA.
Run 0,375 M of BLOOD 0.06 M of BEN 1M of DER DH20
4.0 mL
2.50 mL
0.25 ml
8.25 mL
2
4,0 mL
10,00 mL
025 mL
0.75 mL
3
8.0 mL
2.50 ml
0.25 L
4.25 ot
Table 2. Data on the determination of rate constant of the formation of
KATARA at 28°C.
Concentration of Concentration of Concentration of
Run
BLOOD, M
Rate of
reaction,
M/s
BEN, M
DER, M
1.
0.10
0.010
0.010
2.0 x 10-2
2
0.040
0.010
7.0 x 10-1
0.010
0.010
3.6 x 10-2
4.00-04
3.50E-04
3.00E-04
250-04
2.00 04
Cate of Reaction, M/s
3.
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Transcribed Image Text:CHEMICAL KINETICS AVATAR reaction shown below was subjected to method of initial rates to determine its rate constant. BLOOD + BEN + DER → KATARA The data on the preparation of KATARA and the results of the experiment are presented below. Table 1. Data on the preparation of KATARA. Run 0,375 M of BLOOD 0.06 M of BEN 1M of DER DH20 4.0 mL 2.50 mL 0.25 ml 8.25 mL 2 4,0 mL 10,00 mL 025 mL 0.75 mL 3 8.0 mL 2.50 ml 0.25 L 4.25 ot Table 2. Data on the determination of rate constant of the formation of KATARA at 28°C. Concentration of Concentration of Concentration of Run BLOOD, M Rate of reaction, M/s BEN, M DER, M 1. 0.10 0.010 0.010 2.0 x 10-2 2 0.040 0.010 7.0 x 10-1 0.010 0.010 3.6 x 10-2 4.00-04 3.50E-04 3.00E-04 250-04 2.00 04 Cate of Reaction, M/s 3.
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