Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
Explain how the acidities of alcohols and thiols is reflected by the element effect
Expert Solution
Step 1
- According to Bronsted theory of acid and base, acids are proton donor and base are proton acceptor.
For eg-
HA + B ---> A- + BH
Acid Base Conjugate base Conjugate acid
- Stabilization of conjugate base leads to increase in acidity.
- Acids having lower pH value are acidic.
- pKa defines the stabilization of conjugate base.
- Acids having lower pKa have stable conjugate base and is more acidic.
- One of the factor affecting acidity is element effect.
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