Answered: Estimate the volume of a compound in…

Introduction to Chemical Engineering Thermodynamics

8th Edition

ISBN:9781259696527

Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Chapter1: Introduction

Section: Chapter Questions

Problem 1.1P

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Question

Estimate the volume of a compound in vapor phase using below methods. Fluid is at a state
with T = 800 °R and P = 5 atm.

Assume critical conditions to be: P=30 atm and T=900 R. Also, accentric factor is equal to 0.45.

a. Ideal gas law
b. van der Waals equation
c.
Soave equation
d. Peng-Robinson equation

Definition Definition Law that is the combined form of Boyle's Law, Charles's Law, and Avogadro's Law. This law is obeyed by all ideal gas. Boyle's Law states that pressure is inversely proportional to volume. Charles's Law states that volume is in direct relation to temperature. Avogadro's Law shows that volume is in direct relation to the number of moles in the gas. The mathematical equation for the ideal gas law equation has been formulated by taking all the equations into account: PV=nRT Where P = pressure of the ideal gas V = volume of the ideal gas n = amount of ideal gas measured in moles R = universal gas constant and its value is 8.314 J.K-1mol-1 T = temperature

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