Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Please complete Table A1.

A.1. Cell Potentials
Electrode systems
used in cell
2nl Zn²+
Cul Cuat
2. Zn/Znat
Fest Fest
3. Cu/cuat
AS/Agr
4.Zn/Zn²+
Ag/Agr
5. Zn/2h27
I₂/I-
6. Fe2+ ke
3+
Bra Br
7. Bra / Br
Cia 101
Calculations
Cell potential,
Ecell (volts)
.83
.41
.41
1.3
1.0
.41
.10
Negative
electrode
zn
zn
си
2n
Zn
Fe
CI
Oxidation
reaction
E
Foxidation
in volts
Reduction
reaction
Ereduction
in volts
A. Noting that oxidation occurs at the negative pole in a cell, write the oxidation reaction taking place in each of the cells. The other electrode system
must undergo reduction; write the reduction reaction that occurs in each cell.
B. Assume that E
Ag-Ag
= 0.00 volts (whether in reduction or oxidation). Enter that value in the table for all of the silver electrode systems you used
in your cells. Since Ecell = Eoxidation +Ereductions you can calculate Eº values for all the electrode systems in which the Ag.Ag system was involved.
Enter those values in the table.
C. Using the values and relations in Part B and taking advantage of the fact that for any given electrode system, Exidation =-Eroductions complete the
table of E values. The best way to do this is to use one of the Eº values you found in Part B in another cell with that electrode system. That
potential, along with Ell, will allow you to find the potential of the other electrode. Continue this process with other cells until all the electrode
potentials have been determined.
(continued on following page)
Data and Calculations: Voltaic Cell Measurements.
Experiment 32
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Transcribed Image Text:A.1. Cell Potentials Electrode systems used in cell 2nl Zn²+ Cul Cuat 2. Zn/Znat Fest Fest 3. Cu/cuat AS/Agr 4.Zn/Zn²+ Ag/Agr 5. Zn/2h27 I₂/I- 6. Fe2+ ke 3+ Bra Br 7. Bra / Br Cia 101 Calculations Cell potential, Ecell (volts) .83 .41 .41 1.3 1.0 .41 .10 Negative electrode zn zn си 2n Zn Fe CI Oxidation reaction E Foxidation in volts Reduction reaction Ereduction in volts A. Noting that oxidation occurs at the negative pole in a cell, write the oxidation reaction taking place in each of the cells. The other electrode system must undergo reduction; write the reduction reaction that occurs in each cell. B. Assume that E Ag-Ag = 0.00 volts (whether in reduction or oxidation). Enter that value in the table for all of the silver electrode systems you used in your cells. Since Ecell = Eoxidation +Ereductions you can calculate Eº values for all the electrode systems in which the Ag.Ag system was involved. Enter those values in the table. C. Using the values and relations in Part B and taking advantage of the fact that for any given electrode system, Exidation =-Eroductions complete the table of E values. The best way to do this is to use one of the Eº values you found in Part B in another cell with that electrode system. That potential, along with Ell, will allow you to find the potential of the other electrode. Continue this process with other cells until all the electrode potentials have been determined. (continued on following page) Data and Calculations: Voltaic Cell Measurements. Experiment 32
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