Draw the product(s) of the following Diels-Alder reaction. Explain the formation of the product(s) by suggesting a mechanism. OH + OH 80 F3 F4 A % L O F5 MacBook Air F6 об г F7 * DII F8 O F9
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- Draw the structure of the product of the Diels-Alder reaction below. OCH3 H₂C 11 NO-C=C-CNDraw the structure of the product of the Diels-Alder reaction below. H3C CH3 O || O || + CH3OC-CEC-COCH3True or False: Acetylene is a naturally occurring conjugated diene True or False: The Diels-Alder reaction has the stereochemistry of the dienophile is retained in the product. True or False: When looking at kinetic vs. thermodynamic products the kinetic product predominates at low temperature. True or False: the mechanism of the Diels-Alder reaction is three π bonds break; one σ bond and two π bonds form.
- Mechanism The Diels-Alder reaction is part of a class of reactions known as a cycloaddition reaction. This reaction is specifically a [4+2] cycloaddition which is a concerted (one-step) process in which two new carbon - carbon sigma bonds are formed from two pi bonds. For the first Diels - Alder step of the mechanism fill in the arrows needed for the transformation. The rest of the mechanism is drawn for you. OH Show mechanism arrows for this step! 4 + 2 cycloaddition OH H D- & H+ transfer OH Nuc acyl substitution H L.G.2) Predict the major product for each Diels-Alder reaction. Include stereochemistry where appropriate. H. C=N (a) H H. CH3 CH;O, (b) Ph (c) PhWhat is the diene and dienophile?
- A) Write the mechanism and predict the products for the following reaction. Label each product as the thermodynamic product or the kinetic product. Write a few sentences explaining which product would predominate at low temperature and which would predominate at high temperature and explain the reason for this result. HBr ABd B) Choose reagents that would give the following product in a Diels-Alder reaction: C) Predict the major and minor product for the following Diels-Alder reaction:Which of the following diene(s) cannot undergo the Diels-Alder reaction? II IV %3DDraw the major product of the following Diels-Alder reaction. Use the Bicyclic ring tool and guide points to draw bicyclic molecules. + D X :0 Ś 4 è
- The following is an example of a hetero Diels-Alder reaction, because a noncarbon atom (in this case, an N atom) is involved in bond formation and bond breaking. Draw the curved arrows necessary to account for this transformation. OCH3 OCH3 + N- Hydroquinone, benzene, 25 °C, 90 min 86%4) Identify the reagents to prepare the following compound via Diels-Alder reaction Coalf DI Caotl a) X + .wolt •Looft b) x + you to c) of + Xco coot الاك d) NoneUse arrows to predict the final favored product of the following Diels-Alder reaction. Use the step-wise mechanism to predict the final product of the following reaction. Show stereochemistry at stereogenic centers. NaBH4 CH;OH Use the step-wise mechanism to predict the product of the following reaction. (Excess) H.