Draw the product of an SN2 reaction shown below. Use a dash or wedge bond to indicate stereochemistry of substituents on asymmetric centers. Ignore inorganic byproducts. Br CH3CO₂Na THF Atoms, Bonds and Rings Charges Draw or tap a new bond to see suggestions. Undo Ⓒ Remove 1 Reset Ⓒ Done Drag To Pan
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- Draw the major organic product of the reaction shown below. HO NazCr207 H2SO4, H20 H3C CH3 • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. C opy aste ChemDoodle+ CH2=CH´ `CH3 Draw the molecules on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default. Show the appropriate stereochemistry by choosing the dashed or wedged buttons and then clicking a bond on the canvas. EXP. CONT. .. C N CI Br Marvin JS [1] A by O ChemAxon P FDraw the major organic product of the reaction shown below. -OH Ill You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. K₂Cr₂07 H₂SO4, H₂O Ⓡ Y - [ ]# 2 ChemDoodle 66
- The following reaction should under go a(n) H₂C SN1 Br NaSPh DMF A/ reaction.Dtermine the reagents that can accomplish the rxn CH2OH (1) Reagent ? (2) Reagent ? C9H1202 (4) Reagent ? (3) H+ a. (1) SOC12 (2) 1-propanol; (4) PCC/pyridine b. (1) NaH, (2) acetone, (4) NABH4 c. (1) NaH, (2) epoxide (4) PCC/pyridine d. (1) Jones reagent, (2) NaH, (4) epoxide+ CH2=CH' `CH3 Draw the molecules on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default. Show the appropriate stereochemistry by choosing the dashed or wedged buttons and then clicking a bond on the canvas. L CONT. EXP. L C N CI Br Marvin JS [1] A by O ChemAxon P F -
- 2. Propose electron-pushing arrows for each step of the radical mechanism shown below. PhO,s.-so,Ph jor for > H [w-o [w-o Pho2s-sO,Ph HDraw the major organic product of the reaction shown below. OH CH3 H₂SO4 • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. ▾ Sn [F ? ChemDoodleⓇ баew fopics] Draw the major organic product of the reaction shown below. H2SO4 HO, • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. C opy aste [F ChemDoodle
- c. Snl reactions dominate under polar protic solvents. Increasing the polarity of the solvent will increase the rate of the reaction because the polar solvent will stabilize the dispersed charges on the transition state more than it will stabilize the neutral reactant. Label areas of ô* and & on the molecules of the transition state of the SN1 reaction below: Me Me Ме Me Me H20 Br -Br OH + НО \'H Et Et RDS Et H Et Et transition state not isolable carbocation intermediate not isolableOrganic chem 2 For the reaction: HCI 40° C a Draw the structure(s) of the major product(s) from addition of 1 equivalent of HX to the conjugated diene. • Only give structures deriving from the most stable carbocation. . You do not have to consider stereochemistry. ⚫ Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. อ २ [] ChemDoodle ་1. Indicate if each of the following reactions is likely to go through an SN1 or SN2 mechanism. Briefly justify your choice. a) H3C-1 b) c) Br te d) e) NaCl, H₂O NaCN Br KBr LiBr, DMSO H3C-Cl Br for Nal, CH3OH Br g) h) i) j) Br CH3OH OCH 3 NaI NaBr, DMSO OH-, H₂O OCH3 Br OH