Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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- It is easy to imagine a cyclohexane as a flat hexagon and a lot of the time we draw it that way. Looking at 1,3,5-triethylcyclohexane we cannot tell the stability of the molecule from looking at the flat 2D drawing. Explain why we need to look at the 3D configuration and what conformation (axial,equatorial) would each of the three ethyl groups be in for the most stable configuration.arrow_forwardPlease solve thisarrow_forward6. Use the molecule below to answer the following questions. a) Name the following molecule. b) Why is it necessary to provide R or S designation in order to clearly communicate molecular structure for this molecule? c) How many stereoisomers of this molecule are possible? Which of them are enantiomers to each other? Which are diastereomers? SH ICNarrow_forward
- Draw Newman projections for the anti, eclipsed, gauche and fully eclipsed conformations of Butane. Indicate their relative stabilities and the reasons for your ranking-need to discuss the stresses involved in each case. Using suitable specific conformers of specific structures as examples, explain the difference between (a) angle strain (b) torsional strain and (c) steric strain. Need to draw the confomers and structures 4) Draw the most stable conformers using chair structures of the following: (c) cis-1,2-Dibromocyclohexane (d) trans-1,2-Dibromocyclohexane (e) cis-Decalin (f) trans-Decalin . Draw the most stable conformers of trans-1-Bromo-4-methylcyclohexane and cis-1-Bromo-4-methylcyclohexane. Which is more stable? Explain the reason for your answer. Need to include a discussion of 1,3-Diaxial interactionarrow_forward2. Consider the molecule 4-chloro-3-methylhex-2-ene a) Draw the constitutional structure for the molecule. b) Draw the staggered Newman projection looking along the C4-C5 bond c) Draw the structure for the (Z) geometric isomer of this molecule. Show how you worked that it is Z. d) Identify the chiral carbon atom, and draw the Renantiomer of this molecule. Show how worked out that it is Rarrow_forwardI don't understand how to tell which one goes on which side. When I looked at the answer key to check my answer, I had H/Br and H/NH2 on the wrong sidesarrow_forward
- Write TRUE if the BOLD word/phrase makes the statement correct. Otherwise, write the correct WORD/PHRASE that will make the statement true. If there are two bold words/phrases in a number, write your answer for EACH of the bold words/phrases. 1. The anti-staggered conformation of butane, in which the methyl groups have a dihedral angle of less than 180°, has the highest energy. 2. The formation of 2-methylpropene as side product in the synthesis of tert-butyl chloride is a nucleophilic substitution reaction. 3. The generation of tertiary carbocation is the rate-determining step in tert-butyl chloride synthesis.arrow_forward6. What are conformers? Explain about conformers of butane in light of stability and energy. Also show the conversion of Sawhorse, Fisher and Newman projection of the moleculearrow_forwardConsider the molecule 1,2-dichloro-3-methyl-1-propanol and answer the following questions. Draw the Kekulé representation for this molecule clearly identifying the C1-C2 bond. Draw the Newman projection diagram for the least stable conformation of this molecule looking down the C1-C2 bond. Draw the sawhorse representation of the most stable conformation of this molecule looking down the C1-C2 bond.arrow_forward
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