Draw Haworth projections of both - and -anomers of D-fructose. Indicate which carbon is the anomeric carbon. b) Sucrose is a disaccharide made up of a molecule of D-fructose and D-glucose. Draw the structure of sucrose clearly indicating the linkage between the two monosaccharides and its biological significance. c) Tollen’s reagent is a very mild oxidizing agent which normally oxidize aldehydes but not ketones. However, both glucose and fructose give positive results with Tollen’s reagent and are classified as reducing sugars. Explain how fructose can also give positive results with Tollen’s reagent (illustrate using structures).

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a) Draw Haworth projections of both - and -anomers of D-fructose. Indicate which carbon is the anomeric carbon.

b) Sucrose is a disaccharide made up of a molecule of D-fructose and D-glucose. Draw the structure of sucrose clearly indicating the linkage between the two monosaccharides and its biological significance.

c) Tollen’s reagent is a very mild oxidizing agent which normally oxidize aldehydes but not ketones. However, both glucose and fructose give positive results with Tollen’s reagent and are classified as reducing sugars. Explain how fructose can also give positive results with Tollen’s reagent (illustrate using structures).

Fischer projections of two common monosaccharides are shown below.
CH2OH
CHO
H-
Но-
Но-
-H
H-
-O-
H-
H-
-O-
H-
ČH2OH
ČH2OH
D-Glucose
D-Fructose
Transcribed Image Text:Fischer projections of two common monosaccharides are shown below. CH2OH CHO H- Но- Но- -H H- -O- H- H- -O- H- ČH2OH ČH2OH D-Glucose D-Fructose
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