Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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**Illustration of the Reaction Mechanism for Cyclohexanol with HI** This guide provides a step-by-step illustration of the reaction mechanism of cyclohexanol with hydrogen iodide (HI). The diagrams demonstrate the use of curved arrows to indicate electron movement. The starting materials and intermediates are provided for clarity. Below is the detailed transcription and explanation for each step. **Text Overview:** - The reaction involves cyclohexanol and HI. - Curved arrows are used to depict electron movement during the reaction. - If mistakes are made, the undo button can reverse the last change, or the drawing can be reset via the More menu. **Diagram Steps:** **Step 1:** - **Action:** Draw curved arrows. - **Tools and Options:** Select, Draw, Rings, More, Erase (with options for single, double, triple, and aromatic bonds, and elements C, H, I, O). - **Diagram Details:** - A hexagonal cyclohexanol structure is shown with an -OH group. - An HI molecule is present nearby. - Electron pairs on oxygen are depicted as dots. **Step 2:** - **Action:** Draw curved arrows. - **Diagram Details:** - The HI molecule approaches the oxygen in the OH group. - Curved arrows indicate the movement of electrons from the lone pair on oxygen to hydrogen, and from the H-I bond to the iodine atom. - Oxygen temporarily gains a positive charge, while iodine gains a negative charge. **Step 3:** - **Action:** Draw curved arrows. - **Diagram Details:** - Highlighted intermediate stage where iodine with negative charge is separated. - Cyclohexanol and iodide ion interact, forming the product. **Final Products:** - **Diagram Details:** - The final product shows cyclohexane with an iodine atom, and the separation of water (H₂O). These diagrams help visualize the mechanistic steps involved in the reaction, highlighting the electron movement that leads to the final products.
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Transcribed Image Text:**Illustration of the Reaction Mechanism for Cyclohexanol with HI** This guide provides a step-by-step illustration of the reaction mechanism of cyclohexanol with hydrogen iodide (HI). The diagrams demonstrate the use of curved arrows to indicate electron movement. The starting materials and intermediates are provided for clarity. Below is the detailed transcription and explanation for each step. **Text Overview:** - The reaction involves cyclohexanol and HI. - Curved arrows are used to depict electron movement during the reaction. - If mistakes are made, the undo button can reverse the last change, or the drawing can be reset via the More menu. **Diagram Steps:** **Step 1:** - **Action:** Draw curved arrows. - **Tools and Options:** Select, Draw, Rings, More, Erase (with options for single, double, triple, and aromatic bonds, and elements C, H, I, O). - **Diagram Details:** - A hexagonal cyclohexanol structure is shown with an -OH group. - An HI molecule is present nearby. - Electron pairs on oxygen are depicted as dots. **Step 2:** - **Action:** Draw curved arrows. - **Diagram Details:** - The HI molecule approaches the oxygen in the OH group. - Curved arrows indicate the movement of electrons from the lone pair on oxygen to hydrogen, and from the H-I bond to the iodine atom. - Oxygen temporarily gains a positive charge, while iodine gains a negative charge. **Step 3:** - **Action:** Draw curved arrows. - **Diagram Details:** - Highlighted intermediate stage where iodine with negative charge is separated. - Cyclohexanol and iodide ion interact, forming the product. **Final Products:** - **Diagram Details:** - The final product shows cyclohexane with an iodine atom, and the separation of water (H₂O). These diagrams help visualize the mechanistic steps involved in the reaction, highlighting the electron movement that leads to the final products.
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