Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- Determine the structures of the molecules described in the following problems. Also note, in the combustion of N containing compounds, N2(g) is made. 4. Ornithine is decarboxylated to form putrescine and carbon dioxide. Draw the reaction and using bond energies, predict the enthalpy change for this reaction. 5. Ornithine decarboxylase (the enzyme that catalyzes the reaction in problem 1) is a target for ubiquitylation. In this process, ubiquitin (a small protein) is covalent linked to the target via an “isopeptide bond” between the side chain of lysine and the c-terminus carboxyl group of glycine. Water is released in this process. Predict the enthalpy change of this reaction using bond enthalpies. 6. Often we Hess’s law to determine enthalpies of reactions we are interested in using data from reactions we know. The heat of combustion of glycyl-glycine (dipeptide) is 1972 kJ/mol. The heat of combustion of glycine is -969kJ/mol. Is this enough information to determine the enthalpy…arrow_forwardComplete the equation for the reaction between the following Lewis acid-base pair. Use curved arrows to show the flow of electrons in the reaction and draw the product. Assign lone pairs and radical electrons where appropriate. Apply formal charges where appropriate. • Draw the appropriate electron-flow arrows. • Use the "starting points" menu to revert to the original molecule(s) shown. • Omit + signs between structures. ● / CH3 1- H₂C-C CH3 H در St ? ChemDoodleⓇarrow_forward3. Use curved arrows to show electron movement in the reactant side and draw the product/s of the Lewis (nucleophile-electrophile) reaction. Draw in all lone pairs and charges where appropriate. acid-base -co +arrow_forward
- For 1 and 2, use curved arrows to illustrate the potential overall electron movements or bond changes, and identify the type of reaction by examining the overall chemical transformation. Show A-H bonds as needed.arrow_forwardComplete the equation for the following proton-transfer reaction by using curved arrows to show the flow of electron pairs and drawing the products of the reaction. • Draw all atoms, including hydrogen atoms. Apply formal charges where appropriate. Assign lone pairs and radical electrons where appropriate. • Use the "starting points" menu to revert to the original molecule(s) shown. • Draw the appropriate electron-flow arrows. • Omit + signs between structures. ● ● H-O: == starting points == ↑ TAYY H T H-C-H H-N-H T H در ? ChemDoodlearrow_forwardNeed help with 1-4 please. Will submit another time as well. Pre-laboratory questionsarrow_forward
- Draw all missing reactants and/or products in the appropriate boxes by placing atoms on the canvas and connecting them with bonds. Add charges where needed. Electron flow arrows should start on the electron(s) of an atom or a bond and should end on an atom, bond, or location where a new bond should be created.arrow_forwardCurved arrows are used to illustrate the flow of electrons. Using the provided resonance structures, draw the curved electron-pushing arrows to show the interconversion between resonance hybrid contributors. Be sure to account for all bond-breaking and bond-making steps. :O: Select to Add Arrows :0:arrow_forwardWhat is the missing reactant in this organic reaction? || CH3-C- CH2 -NH2 R No Answer A CH3 CH3-N-CH₂ || C−NH–CH2 C-CH3 + H₂O Specifically, in the drawing area below draw the structure of R. If there is more than one reasonable answer, you can draw any one of them. If there is no reasonable answer, check the No answer box under the drawing area. Note for advanced students: you may assume no products other than those shown above are formed. Click and drag to start drawing a structure. || X :0 Śarrow_forward
- 5. Consider the reaction below and answer the following questions + OH + H₂O a. Draw in ALL missing lone pair electrons as well as electron movement arrows on the reactant side Identify the nucleophile and electrophile on the reactant side b. c. Identify which side of the equilibrium will dominate. d. Draw resonance structures for the organic compound on the product side CHEM 241-Group05. Ormord d ****arrow_forwardA=B When a curved arrow starts from an bond and points to an adjacent atom, the n bond breaks and the o bond remains. This will typically generate two charges. A-B=C Note in the second mechanism shown, if the first curved arrow started from atom C, then atom B would violate the octet rule. A second a bond would need to delocalize. Read the curved arrow in the mechanism shown and draw the product. Be sure to draw lone pairs. Select Draw Rings More Erase C Harrow_forwardOrganic Functional Groups Identifying positions labeled with Greek letters in acids and derivatives If possible, replace an H atom on the a carbon of the molecule in the drawing area with a methyl group substituent, and replace an H atom on the ß carbon with a hydroxyl group substituent. If one of the substituents can't be added for any reason, just don't add it. If neither substituent can be added, check the box under the drawing area. HO Oneither substituent can be added. OH 0/5 Xarrow_forward
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