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- Give the reagent or chemical test that would differentiate the following pairs ofcompounds (Reaction with Br2, Baeyer's reagent, Tollen's reagent). Write chemical equations for the reactions involved. a. benzene and ethylbenzeneb. 1-butyne and 2-butynec. 2-methylpentane and 2-methyl-2-pentened. toluene and 1-methylcyclohexene2. Alcohols Write the complete step-by-step mechanism for the reaction of 3-methyl-2-pentanol with sulfuric acid.1-Bromopropane is synthesized by treating 1-propanol with sulfuric acid (H2SO4) and potassium bromide (KBr) through a simple distillation. What is the inorganic by-product left in the reaction flask following the distillation?
- 4. Using acetylene as the starting material to synthesize 4-methyl-2-pentyne. Please feel free to use any inorganic molecule and organic molecules containing carbon not more two.[Review Topics] [References] Use the References to access important values if needed for this question. Draw a structural formula for the missing organic reactant in the esterification reaction below. ? + CH3OH è *** • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. CH4 OCH3 + H₂O CH₂CH3 Y4. Illustrate each of the following reactions using names and structures; a) The reaction of 2-methyl-propene with hydrogen bromide. b) The condensation of ethanol with butanol. 5. The labels were mixed up on bottles of pentane, hexanal and heptan-1-ol. How could boiling point be used to distinguish between these three colourless liquids? Explain. 6. Illustrate the series of reactions that can be performed to produce propylmethanoate from two alcohols.
- Esterication is the reaction of a carboxylic acid (RCOOH) with an alcohol (R'OH) to form an ester (RCOOR') with loss of water. Equation [1] is an example of an intermolecular esterication reaction. Equation [2] is an example of an intramolecular esterication reaction; that is, the carboxylic acid and alcohol are contained in the same starting material, forming a cyclic ester as product. The equilibrium constants for both reactions are given. Explain why Keq is different for these two apparently similar reactions.2. Using structural diagrams to explain the synthesis of butyl ethanoate from an alkane and an alcohol. Make sure you have the names of the substances and the reaction conditions of the reactions of the steps that consists your synthesis HC-C H- styrene HH ethane-1,2-diol OH НО. JOL -0-H benzene-1.4-dicarboxylic acid.A app.101edu.co 25 Calendar E Reading Li= >> Blackboard MI Apps UT I Apps Submi Question 24 of 31 What will be the major organic product from the acid-catalysed hydration of 1- butene (CH,=CHCH,CH,)? A) 1-butanol B) 2-butanol C) 1-butanoic acid D) butane E) 2-butene +
- II. Write the chemical equation showing reactants, products and catalysts needed (if any) for the following reactions. Write the IUPAC name for the organic compound below its structure. 1. Reaction of p-methylbenzaldehyde with oxygen. 2. Reaction of 4-ethylheptanal with CrO3 and H3O* in the presence of acetone 3. Reaction of 2,4-pentanedione with 2moles of hydrogen 4. Reaction of 4-chlorobutanal with Imole of hydrogen 5. Reaction of two 2-pentanethiol HgC CH3 6. Oxidation of H3C HO, 2,4- dime thyl bwtanol 7. Oxidation of H. 9. Hydrogenation of SH 10. Reaction with chloromethane ofK Draw the major product of this reaction. Ignore inorganic byproducts. x H₂O* Drawing Problem 310 of 20 Drawing Atoms, Bonds and Rings Draw or tap a new bond to see s suggestions Charges Draw ethylcycloheptane in a structural condensed format. < Draw the structural condensed formula of 1-heptyne. Drawing Problem 365 of 20 Draw a terminal alkene that would lead to this product under these conditions. Question 15 of 20 Drawing H₂ Pd/C Problem 297 of 20 Atoms Bonds and Rings Provide the correct common name for the skeletal (line- bond) structure shown here. SuComplete the following chemical reactions. Make sure to draw and name all structural formulae for all organic compounds (both reactants and products). a. Oxidation of 2-pentanol. (K2Cr2O7/H+) → b. Formic acid + Isopropyl alcohol (2-propanol) → c. Acetic acid + Propylamine → d. Dehydration of 2,3-dimethyl-1-butanol (H+/heat) →