Do the magnitudes of these thermodynamic parameters match what you expect for a cycloaddition reaction? Explain

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
100%

Answer number 6 "Calculate  ΔH and ΔS for each reaction. Do the magnitudes of these thermodynamic parameters match what you expect for a cycloaddition reaction? Explain."

I included the calculated results for ΔH and ΔS of each of the 5 reactions below the question. ΔH is in kcal/mol and ΔS is cal/(mol*K). 

6. Calculate AH and AS for each reaction. Do the magnitudes of these
thermodynamic parameters match what you expect for a cycloaddition
reaction? Explain.
Calculated results for AH and AS of each of the 5 reactions:
1. ethene + cis-1,3-butadiene
cyclohexene
AH: - 51.66 kcal/mol
As: - 43.466 cal/(mol*K)
2. cyclopentadiene + maleic anhydride → endo product
AH: -77.04 kcal/mol
As: - 52.292 cal/(mol*K)
3. cyclopentadiene and maleic anhydride -
→ exo product
Дн: - 114.6 kcal/mol
As: -51.76 cal/(mol*K)
4. furan + maleic anhydride
→ endo product
AH: 34.13 kcal/mol
As: -47.35 cal/(mol*K)
5. furan + maleic anhydride-
→ exo product
Дн: - 18.11 kcal/mol
As: - 49.27 cal/(mol*K)
Transcribed Image Text:6. Calculate AH and AS for each reaction. Do the magnitudes of these thermodynamic parameters match what you expect for a cycloaddition reaction? Explain. Calculated results for AH and AS of each of the 5 reactions: 1. ethene + cis-1,3-butadiene cyclohexene AH: - 51.66 kcal/mol As: - 43.466 cal/(mol*K) 2. cyclopentadiene + maleic anhydride → endo product AH: -77.04 kcal/mol As: - 52.292 cal/(mol*K) 3. cyclopentadiene and maleic anhydride - → exo product Дн: - 114.6 kcal/mol As: -51.76 cal/(mol*K) 4. furan + maleic anhydride → endo product AH: 34.13 kcal/mol As: -47.35 cal/(mol*K) 5. furan + maleic anhydride- → exo product Дн: - 18.11 kcal/mol As: - 49.27 cal/(mol*K)
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 4 steps

Blurred answer
Knowledge Booster
Photochemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY