Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Diffusion of hydrogen through a steel wall.
Hydrogen at 150 psia and 80oF is stored in a spherical, steel pressure vessel of inside diameter 4 inches and a wall thickness of 0.125 inch. The solubility of hydrogen in steel is 0.094 lbmol/ft3,and the diffusivity of hydrogen in steel is 3.0 x10-9 cm2/s. If the inner surface of the vessel remains saturated at the existing hydrogen pressure and the hydrogen partial pressure at the outer surfaceis assumed to be zero, estimate the: (a) initial rate of mass transfer of hydrogen through the wall; (b) initial rate of pressure decrease inside the vessel; and (c) time in hours for the pressure to decrease to 50 psia, assuming the temperature stays constant at 80oF.

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