Deuterium (D) is an isotope of H. Both D and H have one proton and one electron; H has no neutrons and D has one. Consequently, D and H have nearly identical behavior, but they can be distinguished from each other experimentally due to their different masses. Therefore, replacing an H with a D in a molecule-deuterium isotope labeling-can provide valuable information about a mechanism. With this in mind, how would you synthesize each of the following deuterium-labeled compounds from the analogous unlabeled compound, using D,0 as your only source of deuterium? Hint: You will have to use two separate proton transfer reactions to synthesize each one. (a) (b) (c) OD D.
Deuterium (D) is an isotope of H. Both D and H have one proton and one electron; H has no neutrons and D has one. Consequently, D and H have nearly identical behavior, but they can be distinguished from each other experimentally due to their different masses. Therefore, replacing an H with a D in a molecule-deuterium isotope labeling-can provide valuable information about a mechanism. With this in mind, how would you synthesize each of the following deuterium-labeled compounds from the analogous unlabeled compound, using D,0 as your only source of deuterium? Hint: You will have to use two separate proton transfer reactions to synthesize each one. (a) (b) (c) OD D.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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