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- 5. In an IR spectrum, the x axis represents wavenumber of the light being absorbed by bond vibrations. The wavenumber is (B) directly proportional to the frequency. (A) directly proportional to the wavelength. (C) inversely proportional to the energy of the wave. (D) None of the above.If the spacings between adjacent vibrational features in a photoelectron spectroscopy experiment decrease, changing by a factor of 1/2, when you deuterate the molecule being ionized, is it more likely that the orbital from which you are ejecting an electron is from a nonbonding orbital, a p orbital localized on a C-C or C-O bond, or a s orbital localized on a C-H bond? Explain.For a non-linear molecule with 5 atoms, how many vibrational modes does it have? 7 6.
- a.) Write down for yourself the secular determinant for the hypothetical molecule linear H3 making the Huckel approximation, using the 1s atomic orbitals from each atom as the basis set. Given that α=-2.00 eV and β= -3 eV, what is the total electronic energy in eV? b.) Write down the secular determinant for the hypothetical molecule cyclic H3 making the Huckel approximation, using the 1s atomic orbitals from each atom as the basis set. Given that α=-2.00 eV and β= -2 eV, what is the total electronic energy in eV?The Infrared spectroscopic method solely can confirm the structure of a molecule. TRUE OR FALSE?7. Consider the Jablonski diagrams below, where So, S₁, and S2 are all singlet electronic states, and T₁ is a triplet electronic state. (So is the electronic ground state.) The horizontal lines indicate the vibrational energy levels in each electronic state. The arrow drawn on the diagram represents the absorption of a UV photon with = 250 nm, promoting the molecule to a high vibrational level in the S₁ state. (The wavelength values here and below are meant as a guide, but this is not really a quantitative question.) Two different processes are described below the diagrams. Read each one, and then draw an appropriate set of arrows on the corresponding diagram to represent the process described. E Diagram #1 - Fluorescence process S₂ S₁ So SS5 T₁ Vo V4 V3 55555 V₂ V₁ V₁ Diagram #2 - Phosphorescence process E S₂ S₁ So 55555 Vo T₁ 7.1 Diagram #1: After the absorption shown in the diagram, the molecule fluoresces, emitting a photon with = 310 nm. ラララララ 7.2 Diagram #2: After the absorption…
- 4G I 5:53 2.30 O Yo 40 52% KB/s 1. The C-C stretch in allene (H,C-C=CH,) is about 1650 cm'; the C-H stretch is about 3,100 cm". Calculate the corresponding wavelengths (in nm) and energies (in kJ/mol) of these vibrations. () IIa.) Based on their ground state electron configurations alone, rank these molecule in order of bond dissociation energy from smallest to greatest:A = N2B = B2C = O2. b.) Based on their ground state electron configurations alone, rank these molecule in order of bond length from smallest to greatest:A = N2B = O2C = NOFor this problem, the molecular orbitals of vitamin C are represented as thick lines. It takes light with a wavelength of 256 nm to cause an electron transition from the HOMO to the LUMO. a. On the diagram, label the HOMO and LUMO. b. If we want the electron to jump from the HOMO to an empty orbital that's higher than the LUMO, should we use light with a wavelength greater than 256 nm or less than 256 nm? (Choose one.) c. To the right of the arrow, draw the thick MO lines and "fishhooks" we would get after performing the big jump from part b. || ++ light
- 1.) Neglecting electron-electron repulsion, write down the ground state of the hydrogen anion H with the electron configuration, 1s?. Include the spatial and spin components. Make sure the wave function (which is the product of space and spin parts) is antisymmetric under the interchange of the two electrons. What is the ground state energy? What is the term symbol for the ground state?Which of the following statements about vibrational frequencies are true? (There is more than one correct answer.) Choice 1 of 3:A. A vibrational frequency corresponds to an internal movement of a molecule, such as a bond lengthening and shortening. Choice 2 of 3:B. An imaginary frequency corresponds to a molecular movement downhill from a saddle point. Choice 3 of 3:C. All molecular structures have at least one imaginary frequency.3. a) Sort the following free atom tem symbols into ascending order of energy: 'F, $F, °S, °P, ?D, ?S, G, 'S b) Predict the microstate table for the s'd' configuration. Assign the ground state term symbol.