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- Estimate the pH that results when the following two solutions are mixed. a) 50 mL of 0.3 M CH3COOH and 50 mL of 0.4 M KOH b) 100 mL of 0.3 M CH3COOH and 50 mL of 0.4 M NaOH c) 150 mL of 0.3 M CH3COOH and 100 mL of 0.3 M Ba(OH)2 d) 200 mL of 0.3 M CH3COOH and 100 mL of 0.3 M Ba(OH)2Using the diagrams shown in Problem 10-117, which of the solutions would have the greatest buffer capacity, that is, greatest protection against pH change, when the following occurs? a. A strong acid is added to the solution. b. A strong base is added to the solution.Calculate the pH of each of the following solutions. (a) 10.0 mL of 0.300 M hydrofluoric acid plus 30.0 mL of 0.100 M sodium hydroxide (b) 100.0 mL of 0.250 M ammonia plus 50.0 mL of 0.100 M hydrochloric acid (c) 25.0 mL of 0.200 M sulfuric acid plus 50.0 mL of 0.400 M sodium hydroxide
- What is a salt? List some anions that behave as weak bases in water. List some anions that have no basic properties in water. List some cations that behave as weak acids in water. List some cations that have no acidic properties in water. Using these lists, give some formulas for salts that have only weak base properties in water. What strategy would you use to solve for the pH of these basic salt solutions? Identify some salts that have only weak acid properties in water. What strategy would you use to solve for the pH of these acidic salt solutions? Identify some salts that have no acidic or basic properties in water (produce neutral solutions). When a salt contains both a weak acid ion and a weak base ion, how do you predict whether the solution pH is acidic, basic, or neutral?Two strategies are also followed when solving for the pH of a base in water. What is the strategy for calculating the pH of a strong base in water? List the strong bases mentioned in the text that should be committed to memory. Why is calculating the pH of Ca(OH)2 solutions a little more difficult than calculating the pH of NaOH solutions? Most bases are weak bases. The presence of what element most commonly results in basic properties for an organic compound? What is present on this element in compounds that allows it to accept a proton? Table 13-3 and Appendix 5 of the text list Kb values for some weak bases. What strategy is used to solve for the pH of a weak base in water? What assumptions are made when solving for the pH of weak base solutions? If the 5% rule fails, how do you calculate the pH of a weak base in water?What is the pH of a solution obtained by mixing 235 mL of NaOH with a pH of 11.57 and 316 mL of Sr(OH)2 with a pH of 12.09? Assume that volumes are additive.
- Strong Acids, Weak Acids, and pH Two 0.10-mol samples of the hypothetical monoprotic acids HA(aq) and HB(aq) are used to prepare 1.0-L stock solutions of each acid. a Write the chemical reactions for these acids in water. What are the concentrations of the two acid solutions? b One of these acids is a strong acid, and one is weak. What could you measure that would tell you which acid was strong and which was weak? c Say that the HA(aq) solution has a pH of 3.7. Is this the stronger of the two acids? How did you arrive at your answer? d What is the concentration of A(aq) in the HA solution described in part c? e If HB(aq) is a strong acid, what is the hydronium-ion concentration? f In the solution of HB(aq), which of the following would you expect to be in the greatest concentration: H3O+(aq), B(aq), HB(aq), or OH(aq)? How did you decide? g In the solution of HA(aq), which of the following would you expect to be in the greatest concentration: H3O+(aq), A+(aq), HA(aq), or OH(aq)? How did you decide? h Say you add 1.0 L of pure water to a solution of HB. Would this water addition make the solution more acidic, make it less acidic, or not change the acidity of the original solution? Be sure to fully justify your answer. i You prepare a 1.0-L solution of HA. You then take a 200-mL sample of this solution and place it into a separate container. Would this 200 mL sample be more acidic, be less acidic, or have the same acidity as the original 1.0-L solution of HA(aq)? Be sure to support your answer.When might a pH meter be better than an indicator to determine the end point of an acid-base titration?Consider the following chemical equilibrium: HCOO¯¯ (aq) + H₂O(aq) = HCOOH(aq) + OH¯(aq). Which of the following graphs represents the perturbation on the system and the change of pH when HCI is added to the container? | pH time || III pH ↑ time Select an answer and submit. For keyboard navigation, use the up/down arrow keys to select an answer. C Q a || = III = d IV pH IV pH time time K Open Χ Your answer
- Complete the table. That is, fill in any missing entries in the second and third columns. Round your entries for for pH to 2 decimal places. solution A B с [H₂O¹] 6.3 × 10 12 mol/L mol/L 0.44 mol/L PH 0 6.60 0 0 about 25 °C. X S ? [H₂O*] to to 2 significant digits, and your entries 圖山圆图Caculate the pH of a solution prepared by mixing 84.7 mL of a 0.25 M aqueous aniline solution (C6H5NH2, Kb = 4.3 x 10-10) with 100. mL of a 0.11 M aqueous nitric acid solution. Your pH should be reported to two places past the decimal point.Complete the data sheet below. DETERMINATION OF pH OF DIFFERENT SOLUTIONS For those who will be using scientific notation, please follow the format below: Example: 0.00455 -> 4.55E-3 45000 -> 4.5E+4 SOLUTION pH [H*), M pOH [он], м 0.0345 M HCI 0.000890 M Sr(OH)2 Mixture of 10.0 mL each of the 2 solutions above