(d) The overall reaction A + B = C + D has a mechanism in elementary reactions given below, with rate coefficients indicated. X is a reactive intermediate. A + B X + C k1 X + B k2 X + C A + B k3 Derive an expression for the rate of formation of product D in terms of rate coefficients and reactant or product concentrations only. Simplify this expression under conditions of k2[B] >> k3[C] and k2[B] << k3[C].

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
icon
Related questions
Question
(d)
The overall reaction A + B = C + D has a mechanism in elementary
reactions given below, with rate coefficients indicated. X is a reactive
intermediate.
A + B
X + C
k1
X + B
D
k2
X + C
A + B
k3
Derive an expression for the rate of formation of product D in terms of rate
coefficients and reactant or product concentrations only. Simplify this
expression under conditions of k2[B] >> k3[C] and k2[B] << k3[C].
Transcribed Image Text:(d) The overall reaction A + B = C + D has a mechanism in elementary reactions given below, with rate coefficients indicated. X is a reactive intermediate. A + B X + C k1 X + B D k2 X + C A + B k3 Derive an expression for the rate of formation of product D in terms of rate coefficients and reactant or product concentrations only. Simplify this expression under conditions of k2[B] >> k3[C] and k2[B] << k3[C].
Expert Solution
steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami…
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Process Dynamics and Control, 4e
Process Dynamics and Control, 4e
Chemical Engineering
ISBN:
9781119285915
Author:
Seborg
Publisher:
WILEY
Industrial Plastics: Theory and Applications
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:
9781285061238
Author:
Lokensgard, Erik
Publisher:
Delmar Cengage Learning
Unit Operations of Chemical Engineering
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:
9780072848236
Author:
Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:
McGraw-Hill Companies, The