Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
Bartleby Related Questions Icon

Related questions

Question
(d) Predict the multiplicity observed for H1 in the ¹H NMR spectrum of 4ax and 4eq. Ignore
couplings to the OH proton and long-range couplings (more than 3 bonds). Assume the following 3-
bond coupling constants between two axial protons Jax-ax, two equatorial protons Jea-eq, and one axial
and one equatorial proton Jax-eq: Jax-ax = 10Hz
Jeg eq = 4Hz
Jax-eq = 3Hz
4ax: multiplicity of H1 =
4eq: multiplicity of H1 =_
(e) Use the coupling constants specified in part (d) and assume that 4ax and 4eq are formed in a
1:1 ratio. Sketch the multiplets that would be observed for H1 in both isomers according to scale:
One multiplet in each box. Represent individual peaks in each multiplet with vertical lines. The height
of each line should be proportional to the intensity of the peak in the multiplet.
2 Hz
2 HE
#1
4eq
4ax
H₂
OH
OH
CI
expand button
Transcribed Image Text:(d) Predict the multiplicity observed for H1 in the ¹H NMR spectrum of 4ax and 4eq. Ignore couplings to the OH proton and long-range couplings (more than 3 bonds). Assume the following 3- bond coupling constants between two axial protons Jax-ax, two equatorial protons Jea-eq, and one axial and one equatorial proton Jax-eq: Jax-ax = 10Hz Jeg eq = 4Hz Jax-eq = 3Hz 4ax: multiplicity of H1 = 4eq: multiplicity of H1 =_ (e) Use the coupling constants specified in part (d) and assume that 4ax and 4eq are formed in a 1:1 ratio. Sketch the multiplets that would be observed for H1 in both isomers according to scale: One multiplet in each box. Represent individual peaks in each multiplet with vertical lines. The height of each line should be proportional to the intensity of the peak in the multiplet. 2 Hz 2 HE #1 4eq 4ax H₂ OH OH CI
SAVE
AI-Generated Solution
AI-generated content may present inaccurate or offensive content that does not represent bartleby’s views.
bartleby
Unlock instant AI solutions
Tap the button
to generate a solution
Click the button to generate
a solution
Knowledge Booster
Background pattern image
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY