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Cumene decomposition is proposed to follow the mechanism (i.e., series of elementary steps) below: k1 Step 1: C + * + C-* k.1 k2 Step 2: C-* + B-* + P k.2 ka Step 3: B-* + B k.3 What would the rate expression be if cumene adsorption (Step 1) were the rate limiting step (i.e., the slow step) and that Steps 2 and 3 were fast steps? Then put the second term of your rate expression in terms of the overall equilibrium constant.

Cumene decomposition is proposed to follow the mechanism (i.e., series of elementary steps) below: k1 Step 1: C + * + C-* k.1 k2 Step 2: C-* + B-* + P k.2 ka Step 3: B-* + B k.3 What would the rate expression be if cumene adsorption (Step 1) were the rate limiting step (i.e., the slow step) and that Steps 2 and 3 were fast steps? Then put the second term of your rate expression in terms of the overall equilibrium constant.

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Cumene decomposition is proposed to follow the mechanism (i.e., series of elementary steps) below: k1 Step 1: C + * + C-* k.1 k2 Step 2: C-* + B-* + P k.z Step 3: k3 B-* 4 B + k.3 What would the rate expression be if cumene adsorption (Step 1) were the rate limiting step (i.e., the slow step) and that Steps 2 and 3 were fast steps? Then put the second term of your rate expression in terms of the overall equilibrium constant.
Transcribed Image Text:Cumene decomposition is proposed to follow the mechanism (i.e., series of elementary steps) below: k1 Step 1: C + * + C-* k.1 k2 Step 2: C-* + B-* + P k.z Step 3: k3 B-* 4 B + k.3 What would the rate expression be if cumene adsorption (Step 1) were the rate limiting step (i.e., the slow step) and that Steps 2 and 3 were fast steps? Then put the second term of your rate expression in terms of the overall equilibrium constant.
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