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Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Copper adopts a face centered cubic (FCC) unit cell with an atomic radius of copper 1.28Å.
Find the edge length, a, for the copper lattice and calculate the density, r, of copper in g/cm3.
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- Platinum forms a face centered unit cell. Calculate the density (in g/cm3 ) of Platinum if the edge length of the unit cell is 3.29 angstroms.arrow_forwardConsider a hypothetical compound in which the anions (0--) make an FCC unit cell. Two types of cations are also present. The first type of cation (A) occupies 4 of the octahedra sites and the second type of cation (B) occupies on the tetrahedral sites. What would be the chemical formula for this compound? Comment on how realistic it is of this many octahedral and tetrahedral sites to be occupied simultaneously.arrow_forwardCalcium sulfide packs into a regular pattern in a three dimensional lattice. The unit cell is the smallest repeating unit of an ionic packing structure. Calcium sulfide has a face-centered cubic unit cell with sulfide ions in octahedral holes. Remember, you calculated the unit cell edge length to be 0.521 nm. If the radius of sulfide ion is 0.184 nm, what is the radius, in nm, of the calcium ion?arrow_forward
- An element has bcc packing with a body-centered cubic unit cell. Its density is 19300 kg/m3 and the unit cell volume is 3.17 x 10-26 L. Calculate the molar mass (g/mol) of the element to three significant figures.arrow_forward3. Calculate the volume of a unit cell of KCl (assume NaCl unit cell). From this, calculate the density of KCl and compare it with the observed value of 1.98 g/cm. em²arrow_forwardMetallic palladium crystallizes in a face-centered cubic lattice, with one Pd atom per lattice point. If the edge length of the unit cell is found to be 388 pm, what is the metallic radius of Pd in pm? r = pmarrow_forward
- The element zirconium has hcp packing with a hexagonal unit cell. The volume of the unit cell is 4.66 x 10-26 L. Calculate the density (kg/m3) of the element.arrow_forwardCalculation of lonic Radii The edge length of the unit cell of LiCl (NaCl-like structure, FCC) is 0.514 nm or 5.14 Å. Assuming that the lithium ion is small enough so that the chloride ions are in contact, as in Figure 10.60, calculate the ionic radius for the chloride ion. Note: The length unit angstrom, Å, is often used to represent atomic-scale dimensions and is equivalent to 10-10 m.arrow_forward3. Draw the lattice for Pt which crystallized in a cubic unit cell with 4 equivalent Pt atoms.arrow_forward
- The crystal structure of magnesium oxide, CaS, is similar to rock salt (NaCl). a) What are the coordination numbers of Ca2+ and S2-. b) What is the type of unit cell that you would expect CaS to have? c) Given that the ionic radii is (Ca2+ = 100 pm and S2- = 184 pm) what is the length and volume of the unit cell.arrow_forwardQUESTION 5 Considering pure metals, which of the following statements is (or are) correct about their cubic unit cells? a) In the FCC (faced center cubic) structure of a pure metal, the edge length of the cubic unit cell (d) and the radius of the metal atom (r) has the following relation: 4 r2 = 2 d2. b) A FCC (face center cubic) unit cell has a greater number of net atoms than a BCC (body center cubic) unit cell has. a) only O b) only Both a) and b) are correct. Neither a) nor b) is correct.arrow_forwardThe density of solid Ni is 8.90 g/cm3. How many atoms are present per cubic centimeter (cm3) of Ni? As a solid, Ni adopts a face-centered cubic unit cell. Based on your answer above, how many unit cells are present per cubic centimeter (cm3) of Ni?arrow_forward
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