Construct the reducible representation for vibration of the CO ligands in the molecule cis-W(CO)5. 2. Reduce the representation to a sum of rreducible representations. 3. Which of the representations are IR active in the C2v point group?

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Chapter1: Chemical Foundations
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Chemistry

1. Construct the reducible representation for vibration of the CO ligands in the molecule cis-W(CO)5.
2. Reduce the representation to a sum of rreducible representations.
3. Which of the representations are IR active in the C2v point group?
4. Assign the corresponding Millikan symbol to the IR bands in the spectra.

IR spectra of cis-(PPH3)2W(CO)4
100
90
80
70
60
50
2100
2050
2000
1950
1900
1850
1800
1750
Wavelength (cm^-1)
%Transmitance
Transcribed Image Text:IR spectra of cis-(PPH3)2W(CO)4 100 90 80 70 60 50 2100 2050 2000 1950 1900 1850 1800 1750 Wavelength (cm^-1) %Transmitance
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