Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Considering a gas containing O2 (20%), N2 (78%), and SO2 (2%), find the composition of the gas on an SO2-free basic, meaning gas without the SO2 in it.
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- Mn in groundwaterA ground water has the following conditions:{Mn2+ (aq)} = 1.0x10 -5pH = 7.0 (i.e., {H+ } = 1.0x10-7)Saturated with oxygen from the atmosphere: {O 2(aq)} = 2.63x10 -4T = 25 °C(a) Write the balanced equation for oxidation of reduced manganese,Mn2+ (aq), by dissolved oxygen (O 2(aq)) to generate MnO 2(s)(manganese dioxide) or MnOOH(s) (manganite), respectively.(b) Determine whether each of the above two reactions isthermodynamically favorable in the ground water. Which phase ofthe manganese oxide is more stable in the ground water?(c) If groundwater is at 5 oC, does oxidation of Mn 2+ (aq) by dissolvedoxygen to generate MnO 2(s) become more or less favorable?Calculate the saturated {Mn 2+ (aq)} assuming the water pH remainsat 7.0 and the dissolved oxygen concentration is 3.73x10 -4 M. 25C and 1 atm Please be as detailed as possible. I want to be able to replicate. Thank you so much. :)arrow_forwardDerive an expression for the molar excess enthalpy of mixing of a mixture described by a molar excess Gibbs free energy of the form gE = X1X2(A21X1 + A12X2) where the constants A21 and A12 are independent of temperature.arrow_forwardThe following chart below is a plot of VLE data from the Dortmund data bank for a binary mixture of acetone (1) and isopropanol (2) at a constant temperature of 328.15 K. Values for the plot are also included in the table below. The saturated vapor curve is magenta, and the saturated liquid curve is cyan. Answer the following questions related to VLE. Pressure (kPa) d) 95 85 75 65 55 45 35 25 0 T=328.15 K 4 0.2 0.4 0.6 Mole fraction x1, y1 0.8 1 -P-X -P-y P (kPa) 30.30 34.393 0.0237 0.1166 0.0642 0.2777 39.93 44.208 0.0971 0.3625 52.026 0.1591 0.4762 59.05 0.2353 0.5722 60.848 0.2687 0.6024 69 0.3879 0.6995 71.177 0.4314 0.7284 75.068 0.5234 0.7655 80.287 0.6084 0.8098 85.038 0.7216 0.8617 85.942 0.7338 0.8729 91.22 0.8569 0.924 94.308 96.91 1 0.9214 0.9629 X₁1 0 y₁ 10 1 The mixing of acetone and isopropanol is non-ideal, and thus must be quantified by an activity coefficient. Given the data points in the table, what is the value of the activity coefficient for acetone in the liquid…arrow_forward
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