Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Aromatic Compounds
Aromatic organic compound or aromatic system is an important class of hydrocarbons under the branch of organic chemistry. Aromatic compounds are also called arenas. The definition of aromatic organic compounds can be stated as a class of organic compound…
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[o Consider the reaction scheme below. Me Me of 210 210 COMI20 OH Hola Holensal,d bus 9 (ii) Explain briefly the observed regioselectivity. Iviz gniw 11 toshsvo beiniinoo noitz9 H® (cat.) With reference to the following reaction scheme: [monqo 1250 901 ayawis luna no br Me NaBH4, Et₂O (i) Draw a curved arrow mechanism to explain the transformation of 9 into 10. of main Me 101 anoitiba Ho HO Me, O Me 10 100 10 Stone & arq tot abortom saogo atowens 1004 Viitzut vford bre ooort mott gnis2 H) osogor (1) Me Miel Me 12 * OH (i) Draw Newman projections for the two lowest energy conformations of ketone 11. (ii) Considering your answer to part (i), identify which is the most reactive conformation of 11 and explain your choice. (iii) Indicate the stereochemistry (at C*) of the major diastereoisomer of alcohol 12. Use appropriate strereochemical drawings to explain your answer.
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Transcribed Image Text:[o Consider the reaction scheme below. Me Me of 210 210 COMI20 OH Hola Holensal,d bus 9 (ii) Explain briefly the observed regioselectivity. Iviz gniw 11 toshsvo beiniinoo noitz9 H® (cat.) With reference to the following reaction scheme: [monqo 1250 901 ayawis luna no br Me NaBH4, Et₂O (i) Draw a curved arrow mechanism to explain the transformation of 9 into 10. of main Me 101 anoitiba Ho HO Me, O Me 10 100 10 Stone & arq tot abortom saogo atowens 1004 Viitzut vford bre ooort mott gnis2 H) osogor (1) Me Miel Me 12 * OH (i) Draw Newman projections for the two lowest energy conformations of ketone 11. (ii) Considering your answer to part (i), identify which is the most reactive conformation of 11 and explain your choice. (iii) Indicate the stereochemistry (at C*) of the major diastereoisomer of alcohol 12. Use appropriate strereochemical drawings to explain your answer.
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