Consider the following system at equilibrium where H° = -18.8 kJ/mol, and Kc = 10.5 , at 350 K.2 CH2Cl2 (g)  CH4 (g) + CCl4 (g)When 0.21 moles of CH2Cl2 (g) are removed from the equilibrium system at constant temperature:The value of Kc _________ (increases, decreases, remains the same.)The value of Qc _________is (greater than, is equal to, is less than) Kc.The reaction must a. run in the forward direction to restablish equilibrium.b. run in the reverse direction to restablish equilibrium.c. remain the same.  It is already at equilibrium. The concentration of CH4 will _________ (increase, decrease or remain the same)

1. For the reaction: 2NH3(g) + CO2(g) (NH2)2CO(s) + H2O(g) AH = - 330 kJ Predict how each of the following changes would impact a reaction that is currently at equilibrium. That is, which way would the reaction progress in order to respond to the change in the system to regain equilibrium (use arrows to show the direction of change that would occur to return back to equilibrium). Explain your reasoning for each part.

Consider the following system at equilibrium where Ho = 18.8 kJ, and Kc = 9.52E-2, at 350 K: CH4(g) + CCl4(g) 2 CH2Cl2(g) If the VOLUME of the equilibrium system is suddenly decreased at constant temperature:   whats the value of Kc   The value of Q   The reaction must

Consider the following equilibrium: N2 (g)+3H2(g)2NH3 (g) AG = -34. kJ Now suppose a reaction vessel is filled with 2.15 atm of nitrogen (N2) and 2.19 atm of ammonia (NH3) at 236. °C. Answer the following questions about this system: OO rise ☐ x10 fall OO Under these conditions, will the pressure of NH3 tend to rise or fall? Is it possible to reverse this tendency by adding H₂? In other words, if you said the pressure of NH3 will tend to rise, can that be changed to a tendency to fall by adding H2? Similarly, if you said the pressure of NH3 will tend to fall, can that be changed to a tendency to rise by adding H₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H2 needed to reverse it. Round your answer to 2 significant digits. yes no ☐ atm S

Consider the following equilibrium: N₂(g) + 3H₂(g)2NH3(g) AG = -34. KJ Now suppose a reaction vessel is filled with 3.40 atm of hydrogen (H₂) and 9.24 atm of ammonia system: Under these conditions, will the pressure of NH3 tend to rise or fall? Is it possible to reverse this tendency by adding N₂? In other words, if you said the pressure of NH3 will tend to rise, can that be changed to a tendency to fall by adding N₂? Similarly, if you said the pressure of NH3 will tend to fall, can that be changed to a tendency to rise by adding N₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of N₂ needed to reverse it. Round your answer to 2 significant digits. rise O fall yes Ono X (NH3) at 736. °C. Answer the following questions about this S

Consider the following system at equilibrium where AH = 268 kJ and Kc = 5.10 × 10-6, at 548 K. NH4Cl(s) NH3(g) + HCl(9) The production of NH3(g) is favored by (indicate true or false): decreasing the temperature: decreasing the pressure (by changing the volume): increasing the volume: adding NH4Cl: adding HCl:

Consider the following system at equilibrium where AH° = -87.9 kJ, and K. = 83.3, at 500 K. PC13(g) + Cl2(g) =PCI5(g) When 0.31 moles of Cl2(g) are removed from the equilibrium system at constant temperature: The value of K. increase. decrease. remain the same. The value of Qc K.. is greater than is equal to is less than The reaction must Orun in the forward direction to restablish equilibrium. Orun in the reverse direction to restablish equilibrium. Oremain the same. It is already at equilibrium. The concentration of PC13 will increase. decrease. remain the same.

4. Toluene, C;H8(1), is an important organic solvent. It is made industrially from methylcyclohexane, C,H14(g): C,H14(g) + heat ? 2C;H8(1) + 3H2(g) State three different changes to an equilibrium mixture of these reacting gases that would shift the reaction toward greater production of toluene. State and explain each change.