Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- 35 Consider the equilibrium system described by the chemical reaction below, which has a value of Kc equal to 3.01 × 10³ at 900 K. If an initial mixture of 0.0216 mol SO2 and 0.0148 mol O2 reacts in a 1.0 L vessel, what will be the concentration of SO3 at equilibrium? 2 SO:(g) + O2(g)= 2 SO:(g) 1 3 NEXT Based on the given values, set up ICE table in order to determine the unknown. 2 SO:(g) O:(g) + 2 SO:(g) Initial (M) 0.0216 0.0148 Change (M) 0.0216 - 2x 0.0148 - x Equilibrium (M) 5 RESET 0.0216 0.0148 1.0 +x +2x -2x 0.0216 + x 0.0216 + 2x 0.0216 - x 0.0216 - 2x 0.0148 + x 0.0148 + 2x 0.0148 - x 0.0148 - 2xarrow_forwardWhat effect will adding additional O2 (g) to the following equilibrium system have, once equilibrium is reestablished? 2 CO2 (g) 2 CO (g) + O2 (g) ∆H ̊ = -514 kJ a) The concentration of CO(g) will increase b) The concentration of CO2 (g) will decrease c) The equilibrium constant for the reaction will increase d) The concentration of CO2 (g) will increasearrow_forwardConsider the following reaction where Kc = 1.20×10-2 at 500 K:PCl5 (g) PCl3 (g) + Cl2 (g)A reaction mixture was found to contain 0.115 moles of PCl5 (g), 4.47×10-2 moles of PCl3 (g), and 4.16×10-2 moles of Cl2 (g), in a 1.00 liter container.Indicate True (T) or False (F) for each of the following: 1. In order to reach equilibrium PCl5(g) must be consumed . 2. In order to reach equilibrium Kc must increase . 3. In order to reach equilibrium PCl3 must be consumed . 4. Qc is less than Kc. 5. The reaction is at equilibrium. No further reaction will occur.arrow_forward
- Consider the following reaction where Kc = 1.29×10-² at 600 K: ? COCI₂ (9) co (g) + Cl₂ (9) A reaction mixture was found to contain 0.107 moles of COCI₂ (g), 5.31×10-² moles of CO (g), and 3.63×10-² moles of Cl₂ (g), in a 1.00 liter container. Indicate True (T) or False (F) for each of the following: F 1. In order to reach equilibrium COCI₂(g) must be produced. 2. In order to reach equilibrium K must decrease . 3. In order to reach equilibrium CO must be produced. Ⓒ 4. Qc is less than Kc. Ⓒ 5. The reaction is at equilibrium. No further reaction will occur.arrow_forwardUse arrows (up / down) to indicate the affect of each of these disturbances (stresses) on the concentration of the reactants and products in this equilibrium: 9 KJ + 2 S02 9) + 02 (9) = 2 S03 (9A disturbance affect on affect on affect on ISO2] [02] ISO3] decrease [SO2] increase [02] increase [SO3] increase pressure decrease temp Period 4 CHEarrow_forward9) Given the following equilibrium reaction below, indicate which direction the reaction will shift when the indicated stresses are applied (à, ß, or none), AND indicate how the K value will change (increase, decrease or stays same) with the stress. P = 1 atm, unless otherwise specified. CO(g) + Cl2(g) ó COCl2(g) H = –107.6 kJ/mol What will happen if:ShiftK value i) The pressure is quadrupled________________________ ii) The reaction temperature is decreased_________________________ iii) More COCl2 gas is added_________________________ iv) The volume is doubled_________________________arrow_forward
- Consider the following equilibrium: N₂(g) + 3H₂(g)2NH3(g) AG = -34. KJ Now suppose a reaction vessel is filled with 3.40 atm of hydrogen (H₂) and 9.24 atm of ammonia system: Under these conditions, will the pressure of NH3 tend to rise or fall? Is it possible to reverse this tendency by adding N₂? In other words, if you said the pressure of NH3 will tend to rise, can that be changed to a tendency to fall by adding N₂? Similarly, if you said the pressure of NH3 will tend to fall, can that be changed to a tendency to rise by adding N₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of N₂ needed to reverse it. Round your answer to 2 significant digits. rise O fall yes Ono X (NH3) at 736. °C. Answer the following questions about this Sarrow_forwardConsider the following system at equilibrium where AH = 268 kJ and Kc = 5.10 × 10-6, at 548 K. NH4Cl(s) NH3(g) + HCl(9) The production of NH3(g) is favored by (indicate true or false): decreasing the temperature: decreasing the pressure (by changing the volume): increasing the volume: adding NH4Cl: adding HCl:arrow_forward▸ 69 20 E Consider the following system at equilibrium at 723 K: N₂(g) + 3H₂(g) 2NH3(g) + 26.6 kcal Indicate whether each individual change would favor the production of NH3(g). Evaluate each change separately, assuming that all other conditions remain constant. D Decreasing the temperature. Decreasing the pressure. Increasing the volume. Removing NH3. Removing H₂. C Submit Answer $ 4 R F % 5 V Retry Entire ♫ FS T G [References] the References to access important values if needed for this question. A 6 v yes no B MacBook Air F6 3 more group attempts remaining Y H & 7 B F7 U N * 8 00 D--ll FB J J ( T 1 M 9 K DD FO O O L ge A F10 P command Previous Email Instructor 4 i A AN = Next> Save and Exit ( { ? 912 option delete retuarrow_forward
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