Consider the electrochemical cell, Ni (s) | NiCl2 (aq, 0.0050 mol kg − 1) | Hg2Cl2 (s) | Hg (l), for which Eo (Ni (s) / Ni2 + (aq)) = -0.257 V and Eo (Hg2Cl2 (s) / Hg (l)) = 0.268 V. A. Identify the balanced half-reactions of reduction and oxidation, b. Calculate the average ionic activity coefficient of NiCl2 from the limit law of Debye-Hückel. vs. Calculate the potential of the electrochemical cell, (2) d. Calculate ΔrG, ΔrGo, and K for the reaction of the electrochemical cell, (3) e. Given that (∂Ecell / ∂T) p = −4.52 × 10−4 V K − 1, calculate ΔrSo and ΔrHo.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Consider the electrochemical cell, Ni (s) | NiCl2 (aq, 0.0050 mol kg − 1) | Hg2Cl2 (s) | Hg (l), for which Eo (Ni (s) / Ni2 + (aq)) = -0.257 V and Eo (Hg2Cl2 (s) / Hg (l)) = 0.268 V. A. Identify the balanced half-reactions of reduction and oxidation, b. Calculate the average ionic activity coefficient of NiCl2 from the limit law of Debye-Hückel. vs. Calculate the potential of the electrochemical cell, (2) d. Calculate ΔrG, ΔrGo, and K for the reaction of the electrochemical cell, (3) e. Given that (∂Ecell / ∂T) p = −4.52 × 10−4 V K − 1, calculate ΔrSo and ΔrHo.
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