
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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( do D , E with explanation asap)

Transcribed Image Text:Consider the cis-1,3-butadiene that has a C2v
point group (structure is shown below). Using
LCAO-MO Hückel approximation in answering the
following questions: -
(A) What are the 4 normalized SALCS?
(B) What is the delocalization energy or
stabilization energy (D. E)?
(Hint: D. E. = 2a + 2B for ethylene)
(C) Identify the HOMO and LUMO orbitals.
(D) Find out the normalized MO wave functions
of the occupied MOs?
(E) Determine the bond order (B.0) between (C1
and C2); and (C2 and C3).
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