Consider the chemical equilibrium, Time left 0:44:30 Fe³+(aq) SCNT (aq) FeSCN² +(aq) The equilibrium concentration of [FeSCN2 +] for this reaction can be determined using a spectrophotometer and is related to the absorbance, A, by the expression: A = el[FeSCN² +1₂ where € = 3300 M cm is the molar absorptivity constant and / = 1 cm is the spectrophotometer cell path length. A solution was made up by mixing 25.0 cm³ of 2.0 x 103 M Fe(NO₂), (aq) with 25.0 cm³ of 2.0 x 103 M KSCN(aq) at 25°. The measured absorbance at equilibrium was 0.225. The initial concentration (at the instant of mixing) of [Fe³+] is Select one: O a. 2.0 x 10¹ M O b. 5.0 x 10-5 M O c. 2.0 x 10-³ M O d. 0.225 M O e. 1.0 x 10³ M 12

Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.91PAE
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Consider the chemical equilibrium,
Time left 0:44:30
Fe³+(aq)+SCN7 (aq) = FeSCN² + (aq)
The equilibrium concentration of [FeSCN2+], for this reaction can be determined using a
spectrophotometer and is related to the absorbance, A, by the expression:
A = el [FeSCN²+1
where e = 3300 M¹ cm is the molar absorptivity constant and / = 1 cm is the
spectrophotometer cell path length. A solution was made up by mixing 25.0 cm³ of
2.0 x 103 M Fe(NO3)3(aq) with 25.0 cm³ of 2.0 x 103 M KSCN(aq) at 25". The measured
absorbance at equilibrium was 0.225.
The initial concentration (at the instant of mixing) of [Fe³+] is
Select one:
O a. 2.0 x 104 M
O b. 5.0 x 10-5 M
O c. 2.0 x 10-³ M
O d. 0.225 M
O e. 1.0 x 10-³ M
Transcribed Image Text:Consider the chemical equilibrium, Time left 0:44:30 Fe³+(aq)+SCN7 (aq) = FeSCN² + (aq) The equilibrium concentration of [FeSCN2+], for this reaction can be determined using a spectrophotometer and is related to the absorbance, A, by the expression: A = el [FeSCN²+1 where e = 3300 M¹ cm is the molar absorptivity constant and / = 1 cm is the spectrophotometer cell path length. A solution was made up by mixing 25.0 cm³ of 2.0 x 103 M Fe(NO3)3(aq) with 25.0 cm³ of 2.0 x 103 M KSCN(aq) at 25". The measured absorbance at equilibrium was 0.225. The initial concentration (at the instant of mixing) of [Fe³+] is Select one: O a. 2.0 x 104 M O b. 5.0 x 10-5 M O c. 2.0 x 10-³ M O d. 0.225 M O e. 1.0 x 10-³ M
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