Consider rotation about the indicated bond in the molecule below. Which Newman Projection formula best represents the most stable conformer of the molecule with respect to rotation about the indicated bond? [As noted below: there is no steric strain between -H and -Et that have a gauche, staggered relationship] H CH3 Br-C-C-CH₂CH3 HH H H Br CH3CH₂ 1 CH3 H CH3CH₂ H Br H₂C || H H H₂C H Br H ||| Select one: OA. I OB. II O C. III D. All conformers have identical energies. CH₂CH3 H NOTE CH3CH₂ no steric strain

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
**Rotational Stability in Newman Projections**

Consider rotation about the indicated bond in the molecule below. Which Newman Projection formula best represents the most stable conformer of the molecule with respect to rotation about the indicated bond? [As noted below: there is no steric strain between -H and -Et that have a gauche, staggered relationship]

**Diagrams:**
- There is a molecular diagram at the top showing a compound with a central carbon atom bonded to a bromine, a hydrogen, and an ethyl group (CH₂CH₃).
- Below are three Newman projection diagrams labeled I, II, and III:
  - **I**: Shows bromine and an ethyl group in a staggered formation with hydrogen atoms.
  - **II**: Shows bromine and hydrogen in a staggered formation with an ethyl group and other hydrogen atoms.
  - **III**: Shows the ethyl group and hydrogen staggered, with bromine positioned next to hydrogen atoms.
- A note box to the right emphasizes that there is "no steric strain" when CH₃CH₂ and H are in this position.

**Select one:**
- A. I
- B. II
- C. III
- D. All conformers have identical energies.

The diagram in the note suggests that the absence of steric strain occurs when larger groups are staggered.
Transcribed Image Text:**Rotational Stability in Newman Projections** Consider rotation about the indicated bond in the molecule below. Which Newman Projection formula best represents the most stable conformer of the molecule with respect to rotation about the indicated bond? [As noted below: there is no steric strain between -H and -Et that have a gauche, staggered relationship] **Diagrams:** - There is a molecular diagram at the top showing a compound with a central carbon atom bonded to a bromine, a hydrogen, and an ethyl group (CH₂CH₃). - Below are three Newman projection diagrams labeled I, II, and III: - **I**: Shows bromine and an ethyl group in a staggered formation with hydrogen atoms. - **II**: Shows bromine and hydrogen in a staggered formation with an ethyl group and other hydrogen atoms. - **III**: Shows the ethyl group and hydrogen staggered, with bromine positioned next to hydrogen atoms. - A note box to the right emphasizes that there is "no steric strain" when CH₃CH₂ and H are in this position. **Select one:** - A. I - B. II - C. III - D. All conformers have identical energies. The diagram in the note suggests that the absence of steric strain occurs when larger groups are staggered.
Expert Solution
Step 1

Chemistry homework question answer, step 1, image 1

steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
Alkanes and Cycloalkanes
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY