Consider a saturated solution of AgBr in 0.010 M NH3. AgBr (s) Ag* + NH3 (aq) 5 Ag(NH3)* S Ag* + Br Ksp = 5.0 x10-13 Kf = 2.04 x10³ Ag(NH3)* + NH3 (aq) 5 Ag(NH3)2* K¢ = 8.13 x10³ %3D %3D NH3 (aq) + H2O 5 NH4* + OH- Kb = 1.75 x10$ %3D H2O S H* + OH¯ Kw = 1.00 x10-14 %3D a. How many unknown concentrations must be solved? How many equations are require: b. Write a charge balance equation for the system. Write a mass balance equation for the system.

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Chapter1: Chemical Foundations
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Consider a saturated solution of AgBr in 0.010 M NH3.
AgBr (s) 5 Ag* + Br
Ag* + NH3 (aq) 5 Ag(NH3)*
Ag(NH3)* + NH3 (aq) 5 Ag(NH3)2* Kr
Ksp = 5.0 x10-13
Kf = 2.04 x10³
8.13 x103
NH3
+ H2O 5 NH4* + OH-
Kb = 1.75 x105
(aq)
H2O S H* + OH¯
Kw = 1.00 x10-14
a. How many unknown concentrations must be solved? How many equations are required?
b. Write a charge balance equation for the system.
c. Write a mass balance equation for the system.
Transcribed Image Text:Consider a saturated solution of AgBr in 0.010 M NH3. AgBr (s) 5 Ag* + Br Ag* + NH3 (aq) 5 Ag(NH3)* Ag(NH3)* + NH3 (aq) 5 Ag(NH3)2* Kr Ksp = 5.0 x10-13 Kf = 2.04 x10³ 8.13 x103 NH3 + H2O 5 NH4* + OH- Kb = 1.75 x105 (aq) H2O S H* + OH¯ Kw = 1.00 x10-14 a. How many unknown concentrations must be solved? How many equations are required? b. Write a charge balance equation for the system. c. Write a mass balance equation for the system.
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