Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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The table shown here lists the molar heats of vaporization
for several organic compounds. Use specific examples from
this list to illustrate how the heat of vaporization varies
with (a) molar mass, (b) molecular shape, (c) molecular
polarity, (d) hydrogen-bonding interactions. Explain these
comparisons in terms of the nature of the intermolecular
forces at work. (You may find it helpful to draw out the
structural formula for each compound.)

Compound
Heat of Vaporization (kJ/mol)
CH3CH2CH3
19.0
CH;CH,CH,CH,CH;
27.6
CH;CHB1CH3
31.8
CH;COCH3
32.0
CH3CH2CH,Br
33.6
CH;CH,CH2OH
47.3
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Transcribed Image Text:Compound Heat of Vaporization (kJ/mol) CH3CH2CH3 19.0 CH;CH,CH,CH,CH; 27.6 CH;CHB1CH3 31.8 CH;COCH3 32.0 CH3CH2CH,Br 33.6 CH;CH,CH2OH 47.3
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