
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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The complex [Fe(H2O)6]+2 exhibits only σ-donor behavior.
Using ligand field theory, draw the molecular orbital diagram mixing the d-orbitals on the metal and the molecular orbitals on the ligands and fill in the available electrons.
What is the nature of the t2g orbitals that are part of Δo, bonding, antibonding, or non-bonding? Explain your answer.
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- What is the charge on each of the following complex ions? hexaaquairon(II), [Fe(H2O)6]? tris(carbonato)ferrate(III), [Fe(CO3)3]? diaquatetrachlorovanadate(III), [V(H2O)2Cl4]? Express the charges numerically, in the order that the complexes are listed, separated by commas. For a nonzero charge, be sure to include the sign (e.g., +1,-2,+3).arrow_forward[Fe(OH₂)6]²+ is paramagnetic whereas [Fe(CN)6]4 is diamagnetic. Which of the following provides the best explanation for this? As a weak field ligand, H₂O induces a larger A, than CN, which is a strong field ligand. [Fe(OH₂)6]²+ is a positively charged complex whereas [Fe(CN)6]4 is a negatively charged complex. O [Fe(OH₂)6]²+ has fewer paired electrons because the pairing energy is larger than A.。. O [Fe(OH₂)6]²+ is a low spin complex while [Fe(CN)6]4 is a high spin complex.arrow_forwardQ4/ geometrical isomerism is found in square planar and octahedral complexes but not found in tetrahedral complexes? Q5/ Which of the following can function as a bidentate ligand? NH₁, CO, CO, OHarrow_forward
- Make a prediction about each structures' splitting energy relative to an octahedral complex with all water ligands. Provide some theoretical basis for these claims (see the protocol for Part 2 and textbook chapter 22 to deepen understanding of these concepts). the structure is K3[Fe(C2O4)3]· 2 H2Oarrow_forwardWrite the valence electron configuration for the cobalt ions in the complexes [Co(H2O)6]2+ and draw labelled crystal field splitting diagram (relative to the spherical ion) and calculate the magnetic moment, µ(spin-only) of the cobalt ion in the complexes and as a free metal ion.arrow_forwardAssign the type of isomerism to the following isomers: [Pt(NH3)4][PdCl4] and [Pd(NH3)4][PtCla] hydrate isomers linkage isomers coordination isomers ionization isomersarrow_forward
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