CI C6H1003S (product A) + 2 HCI HO, OH

Explain why meta hydrogens in phenol are more deshielded than ortho and para hydrogen atoms.

Complete the following reaction. A C-NH2 B LiAlH4 ether -CH2NH2 C -NH2 D -OH

A benzene ring alters the reactivity of a neighboring group in the so-called “benzylic” position, similarly to how a double bond alters the reactivity of groups in the “allylic” position. Benzylic cations, anions, and radicals are all more stable than simple alkyl intermediates. a) Use resonance structures to show the delocalization of the positive charge, negative charge, and unpaired electron of the benzyl cation, anion, and radical.

Provide the reagents necessary to carry out the following transformations. Some of these may be multiple steps syntheses and may involve the use of other organic molecules. a. b. CH₂ OH Ph OH

7. Consider the following three step reaction. [4 (a) Add curved arrows in Step [1] to show the movement of electrons. H Lö: HÖ [1] + H-Ci: (b) Use the curved arrows drawn in Step [2] to identify the structure of X. X is converted in Step [3] to phenol and HCI. [2] + H-CI: [3] phenol