Chemists graph kinetic data to determine rate constants and the order of reactions. Analyze this data. If the slope is -0.0440 for this reaction, determine the rate constant, k, for this reaction.
Chemists graph kinetic data to determine rate constants and the order of reactions. Analyze this data. If the slope is -0.0440 for this reaction, determine the rate constant, k, for this reaction.
Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.48PAE: 11.48 The following data were collected for the decomposition of NT),-: Time, f (min) [N2Os] (mol...
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Question 13.c of 13
Chemists graph kinetic data to
determine rate constants and the
order of reactions. Analyze this
data.
If the slope is -0.0440 for this
reaction, determine the rate
constant, k, for this reaction.
1
4
7
+/-
2
5
8
S-1
3
60
9
O
Submit
Tap here or pull up for additional resources
XU
x 100](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F4782c8f2-2aa4-442e-aef6-a61e0f118e5b%2Fc972b43f-a880-4101-bd7f-7d03edbe376d%2Ft7s584_processed.jpeg&w=3840&q=75)
Transcribed Image Text:5:34
Question 13.c of 13
Chemists graph kinetic data to
determine rate constants and the
order of reactions. Analyze this
data.
If the slope is -0.0440 for this
reaction, determine the rate
constant, k, for this reaction.
1
4
7
+/-
2
5
8
S-1
3
60
9
O
Submit
Tap here or pull up for additional resources
XU
x 100
Expert Solution
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Step 1
(i) The units of rate constant for first order reaction are time-1.
In the given question, the units of rate constant are given as s-1 where s is the unit of time. So, the reaction is first order.
(ii) The integrated rate law for the first order reaction is . If a plot of ln[A] vs time (t) is a straight line then the reaction is first order with respect to "A". Here,
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