Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- A student runs two experiments with a constant-volume "bomb" calorimeter containing 1100. g of water (see sketch at right). First, a 7.000 g tablet of benzoic acid (CH₂CO₂H) is put into the "bomb" and burned completely in an excess of oxygen. (Benzoic acid is known to have a heat of combustion of 26.454 kJ/g.) The temperature of the water is observed to rise from 15.00 °C to 53.26 °C over a time of 12.3 minutes. Next, 5.420 g of acetylene (C₂H₂) are put into the "bomb" and similarly completely burned in an excess of oxygen. This time the temperature of the water rises from 15.00 °C to 74.42 °C. Use this information, and any other information you need from the ALEKS Data resource, to answer the questions below about this reaction: Is this reaction exothermic, endothermic, or neither? If you said the reaction was exothermic or endothermic, calculate the amount of heat that was released or absorbed by the reaction in the second experiment. Calculate the reaction enthalpy ΔΗ. per mole of…arrow_forwardA 6.78 g sample of methanol was combusted in a bomb calorimeter. The temperature of the calorimeter increased by 12.7 °C. If the molar mass of methanol is 32.04 g/mol, and the heat capacity of the calorimeter is 5,104 J/°C, what is the molar AE for this reaction, in kJ/mol? Do not report units in your answer. Report your answer to one decimal place and include the correct sign.arrow_forward[2] When 1.045 g of CaO is added to 50.0 ml of water at 22.0 °C in a coffee-cup calorimeter, the temperature of the water increases to 29.3 °C. Assume that the specific heat and density of the solution is 4.184 J/g-°C and 1.00g/ml, respectively. The heat capacity of the calorimeter is 18.0 J/°C. Calculate AH for the reaction. CaO(s) + H2O(1) –→ Ca(OH)2(aq); AH =arrow_forward
- When 1.836 grams of sucrose (Molar mass 342.3 g/mol) is burned in a bomb calorimeter, the temperature of the calorimeter increases from 22.41°C to 26.63°C. If the heat capacity of the calorimeter is 4.900 kJ/°C, what is the heat of combustion of sucrose?arrow_forwardIn a coffee cup calorimeter, 50.0 mL of 1.00 M NaOH and 50.0 rnL of 1.00 M HCI are mixed. Both solutions were originally at 24.6 °C. After the reaction, the final temperature is 31.3 °C. Given that the density of NaCl solution is 1.038 g/mL and the specific heat of NaCl solution is 3.87 J/g-°C, calculate the ΔHneut/mole for the reaction of HCl with NaOH. Assume that no heat is lost to the surroundings.arrow_forwardA 5.1-gram piece of gold jewelry isremoved from water at 100.0°C and placed in a coffee-cup calorimeter containing 16.9 gof water at 22.5°C (specific heat of water is 4.184 J/g · °C). The equilibrium (final)temperature of the water and jewelry is 23.2°C. The calorimeter constant is known fromcalibration experiments to be 1.54 J/°C. What is the specific heat (in J/g · °C) of this pieceof jewelry? If the tabulated value of the specific heat of gold is 0.129oC, is the jewelrypure gold?arrow_forward
- A student runs two experiments with a constant-volume "bomb" calorimeter containing 1400. g of water (see sketch at right). First, a 5.000 g tablet of benzoic acid (CH-CO₂H) is put into the "bomb" and burned completely in an excess of oxygen. (Benzoic acid is known to have a heat of combustion of 26.454 kJ/g.) The temperature of the water is observed to rise from 21.00 °C to 42.00 °C over a time of 8.5 minutes. Next, 5.190 g of ethylene (C₂H4) are put into the "bomb" and similarly completely burned in an excess of oxygen. This time the temperature of the water rises from 21.00 °C to 63.35 °C. Use this information, and any other information you need from the ALEKS Data resource, to answer the questions below about this reaction: Is this reaction exothermic, endothermic, or neither? If you said the reaction was exothermic or endothermic, calculate the amount of heat that was released or absorbed by the reaction in the second experiment. exothermic C₂H₂(g) + 30₂(g) → 2CO₂(g) + 2H₂O(g) Be…arrow_forwardThe combustion of 0.1566 g benzoic acid increases the temperature of a bomb calorimeter by 2.51°C. Calculate the heat capacity of this calorimeter. (The energy released by combustion of benzoic acid is 26.42 kJ/g.) Heat capacity = kJ/°C A 0.2195-g sample of vanillin (Cg H3 O3) is then burned in the same calorimeter, and the temperature increases by 3.21°C. What is the energy of combustion per gram of vanillin? Energy = kJ/g Per mole of vanillin? Energy = kJ/molarrow_forwardA student has a coffee-cup calorimeter with 50.0 g of water at 21.5oC. They introduce 15.525 g of magnesium metal initially at 100.0oC. The final temperature of the calorimeter came to 27.2oC. What is Cmagnesium in J/g-K?arrow_forward
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