
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Step 1: The Concept
An electrochemical cell is made up of two half-cell compartments and carries out the conversion of the chemical energy of a spontaneous reaction into electrical energy.
Both half-cell compartments have a metal rod/stripe called the electrode, that is dipped in a suitable electrolytic solution.
Each electrode (anode or cathode) has a certain standard electrode potential that measures its ease of getting reduced.
The difference between the standard electrode potentials of the cathode and the anode is called the standard cell potential.
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Step 2: The Approach
The relationships between the Gibbs free energy, the equilibrium constant, and the standard cell potential are given below:
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