Homework Help is Here – Start Your Trial Now!
Science
Chemistry
Chapman's (O. L. Chapman, then at Iowa State and later at UCLA) classic total synthe- sis of (+)-carpanone is so remarkably simple that it is used as an undergraduate labora- tory preparation. It is modeled on a possible biosynthetic route for this lignan-derived natural product. Phenol oxidations figure prominently in many such biosyntheses of natural products. In one step, this reaction creates no less than five contiguous chiral centers, all in the correct relative configuration. K* tert-Buo- DMSO ОН HO. [0] (+)-Carpanone

Chapman's (O. L. Chapman, then at Iowa State and later at UCLA) classic total synthe- sis of (+)-carpanone is so remarkably simple that it is used as an undergraduate labora- tory preparation. It is modeled on a possible biosynthetic route for this lignan-derived natural product. Phenol oxidations figure prominently in many such biosyntheses of natural products. In one step, this reaction creates no less than five contiguous chiral centers, all in the correct relative configuration. K* tert-Buo- DMSO ОН HO. [0] (+)-Carpanone

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
See similar textbooks
icon
Related questions
Question

Would you expect the product to be racemic or a single enantiomer?

Chapman's (O. L. Chapman, then at Iowa State and later at UCLA) classic total synthe- sis of (+)-carpanone is so remarkably simple that it is used as an undergraduate labora- tory preparation. It is modeled on a possible biosynthetic route for this lignan-derived natural product. Phenol oxidations figure prominently in many such biosyntheses of natural products. In one step, this reaction creates no less than five contiguous chiral centers, all in the correct relative configuration. K* tert-Buo- DMSO ОН HO. [0] (+)-Carpanone
Transcribed Image Text:Chapman's (O. L. Chapman, then at Iowa State and later at UCLA) classic total synthe- sis of (+)-carpanone is so remarkably simple that it is used as an undergraduate labora- tory preparation. It is modeled on a possible biosynthetic route for this lignan-derived natural product. Phenol oxidations figure prominently in many such biosyntheses of natural products. In one step, this reaction creates no less than five contiguous chiral centers, all in the correct relative configuration. K* tert-Buo- DMSO ОН HO. [0] (+)-Carpanone
Expert Solution
Step 1

Stereochemistry is a branch of chemistry that deals with the arrangement of atoms in 3D. It explains the phenomenon of chirality and configuration.

steps

Step by step

Solved in 2 steps

Blurred answer
Knowledge Booster
Stereochemistry in Organic Reactions
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
SEE MORE TEXTBOOKS