
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Transcribed Image Text:16. Rank the species below in order of increasing nucleophilicity in protic solvents:
CH3CO2-, CH3S-, HO-, H2O.
Answer:
A. H2O <CH3CO2-<HO-< CH3S-
B. CH3CO2-<H2O<HO-<CH3S-
C. CH3S-<CH3CO2-<HO-<H2O
D. H2O<CH3S-<CH3CO2-<HO-
17. Assuming no other changes, what is the effect of doubling only the concentration of the alkyl halide
in the SN1 reaction below?
(CH3) 3CBr + I
A) no change
B) doubles the rate
C) triples the rate
D) quadruples the rate
E) rate is halved
(CH3) 3CI + Br
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