Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Question
Allylic carbocation stability is atfected by both the naure of u Cal by the degree of substitution of the double bond The latter is typically the dominant effect and so a primary allylic car trisubstituted double bond is more stable than a tertiary allylic carbocation with a monosubstituted double bond. Electrophilic addition to a conjugated diene is temperature dependent where reaction at or below room temperature ty mixture of products in which the 1,2 adduct (or direct addition product) predominates, this is termed kinetic control A temperatures the reactions have time to come to equilibrium and typically the 1,4 adduct (or conjugate addition produ predominate, this is termed thermodynamic control. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions CH3 CH3 CH3 CH3 H2C H2C CI
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Transcribed Image Text:Allylic carbocation stability is atfected by both the naure of u Cal by the degree of substitution of the double bond The latter is typically the dominant effect and so a primary allylic car trisubstituted double bond is more stable than a tertiary allylic carbocation with a monosubstituted double bond. Electrophilic addition to a conjugated diene is temperature dependent where reaction at or below room temperature ty mixture of products in which the 1,2 adduct (or direct addition product) predominates, this is termed kinetic control A temperatures the reactions have time to come to equilibrium and typically the 1,4 adduct (or conjugate addition produ predominate, this is termed thermodynamic control. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions CH3 CH3 CH3 CH3 H2C H2C CI
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