Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Cell
Zn-Cu
Cu-Pb
Cu-Fe
Zn-Pb
Fe-Zn
Fe-Pb
EXP. 3 VOLTAIC CELLS
POST-LAB REPORT WORKSHEETS
Part 2 - Measurement of Cell Potentials
1. Note: Because [Fe²] # 0.5 M. the experimental voltages can be expected to
deviate from the calculated voltages (using the Nernst equation) where Fe²+
half-cells are involved.
Experimental
Voltage
Readings and
Average
1.092+ 1,092
2
= 1.095 V
0.465 +0.465
= 0.465 V
0.028 +0.027
= 00275V
0.6%0+ 0.628
20.629 V
0.321 +0.322
2
= 0.3215 V
0.002 1 0.004
2
At which metal
does reduction
occur?
Ch
Cult (agite
→→→>Cur
Си
+0.16V
Си
+0.16V
40-160
Zn
-0,76V
Zn
-0.76✓
Pb
At which metal
does oxidation
occur?
Zn
Zn(a)+26
→ In (s)
-0.134
-0.76V
Pb.
-0.13V
Pb
+0.77V
-0.13V
Fe
+0.77
Which metal is
the stronger
reducing
agent?
2n
-076 V
Pb
-0.13V
Fe
+0.77V
Pb
-0.13 V
Fe
+0.77
Fe
Calculated
Voltage
(assume 0.5 M)
-0.003 V
+0.77
+0.77
2. On the basis of the calculated voltages, write the order for the reducing strength
of the four metals (Zn, Cu, Pb, Fe), in order of decreasing reducing strength.
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Transcribed Image Text:Cell Zn-Cu Cu-Pb Cu-Fe Zn-Pb Fe-Zn Fe-Pb EXP. 3 VOLTAIC CELLS POST-LAB REPORT WORKSHEETS Part 2 - Measurement of Cell Potentials 1. Note: Because [Fe²] # 0.5 M. the experimental voltages can be expected to deviate from the calculated voltages (using the Nernst equation) where Fe²+ half-cells are involved. Experimental Voltage Readings and Average 1.092+ 1,092 2 = 1.095 V 0.465 +0.465 = 0.465 V 0.028 +0.027 = 00275V 0.6%0+ 0.628 20.629 V 0.321 +0.322 2 = 0.3215 V 0.002 1 0.004 2 At which metal does reduction occur? Ch Cult (agite →→→>Cur Си +0.16V Си +0.16V 40-160 Zn -0,76V Zn -0.76✓ Pb At which metal does oxidation occur? Zn Zn(a)+26 → In (s) -0.134 -0.76V Pb. -0.13V Pb +0.77V -0.13V Fe +0.77 Which metal is the stronger reducing agent? 2n -076 V Pb -0.13V Fe +0.77V Pb -0.13 V Fe +0.77 Fe Calculated Voltage (assume 0.5 M) -0.003 V +0.77 +0.77 2. On the basis of the calculated voltages, write the order for the reducing strength of the four metals (Zn, Cu, Pb, Fe), in order of decreasing reducing strength.
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