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- Acid anhydride Carboxylic Acid H₂C CH₂OH H₂O CH,OH CH3 Ester H₂C O CH₂OH 1. CH₂MgBr 2. H₂O* Acid chloride CH,CH,NH, Tertiary alcohol AmideCH2 H3C H3C COOH Reagents e. PB13 f. NaCN then H3O* g. NBS, CCI4 h. CrO3, H2SO4 а. HBr b. Mg, ether c. CO2, ether then H3O* d. BH3, THF then H2O2, OH"H 1. KCN, H2O 2. NaBH4, MeOH 3. cyclopentanone TSOH, benzene heat Ph Ph oloof & or OH D B Ph
- Compound A Compound F HCI CH3OH H₂SO4 Compound B CH3 CH₂ CH₂ Cl Compound E NaOH K₂Cr₂O7 H₂SO4 Compound C K₂Cr₂O7 H₂SO4 Compound D a. Draw the structural formulas of compounds A, C, D, E and F in the boxes provided above.(b) P alcohol OH AVI // 1. H3PO4 2. Os04 3. NaHSO3 Q در ? Ⓡ ChemDoodleQUESTION 2 The following is a proposed synthetic strategy that uses one starting alcohol in two separate single-step reactions (I and II) to make a pair of diene and dienophile which together undergo a Diels-Alder reaction to give a Diels-Alder product. The Diels-Alder product is subsequently converted to the final ether in a three-step synthesis (III, IV and V). Identify the reagent(s) from Table I required for each of those three sysnthese and place the number (A1, A2 reagent(s) in the given box right next to the corresponding step numbers (I to V) of the synthesis. DO NOT fill in any box with more than one number. (Note: This question is different from the previous synthesis question which allows two numbers for each box). You will be graded based on the number in each box. Do not fill in any single box with more than one number. Do not leave any box blank. B1, B2..., or C1, C2 ...) that represents the (I) diene OH (III, IV and V) Diesl-Alder product (II) dienophile Table I Number…
- 1. Which functional group is found in aldehydes? a. CHO b. -CH;OH c. -COOH d. RCOR' 2. Which functional group is found in ketones? a. -CHO CH:OH c. -COOH RCOR' 3. Which structural feature is common to aldehydes and ketones? a, an oxygen atom bonded to both a carbon atom and a hydrogen atom b. an oxygen atom bonded to two carbon atoms c. an oxygen atom double bonded to a carbon atom d. two oxygen atoms bonded to the same carbon atom 4. What is the IUPAC name for the following compound? a. I-pentaldehyde b. l-pentanal c. pentanal d. pentanealdehyde Cetoa of FiCream of tartar is a white powder sometimes used in baking. (It's what separates a tangy, chewy snickerdoodle from an ordinary cinnamon-coated sugar cookie. The acid in the cream of tartar gives snickerdoodles their distinctive tangy flavor, and the chew happens because cream of tartar prevents sugar in the cookie dough from crystalizing into crunchiness. Allrecipies.com) Cream of tartar (KHC4H4O6) is the conjugate base salt of tartaric acid (shown to the right). The Ka for another similar acid is 8.7×10-3. What is the standard Gibb's free energy (in kJ/mol) for the dissociation of that other acid?Predict reagents needed to complete this E1 elimination reaction. Br
